Karaarslan, MuhsinDemircan, Aydin2019-08-012019-08-0120070970-7077https://hdl.handle.net/11480/5370A variety of key precursors to the intramolecular Diels-Alder (IMDA) reaction of furan diene have been prepared via facile alkylation. Subsequently, rigid heterotricyclic chlorides 5a-e possessing oxygen, nitrogen and sulfur have been synthesized by employing a thermal IMDA reactions. Use of bulky protecting group on nitrogen 5a-b, such as t-butoxy group, can be utilized to encourage cycloaddition reactions that otherwise does not proceed.eninfo:eu-repo/semantics/closedAccessintramolecular Diels-AldercycloadditionfurfurylchloroalkenesArticle194299930062-s2.0-34547147864Q4WOS:000251463400079Q4