Investigation of the electro-oxidation of artificial Black Sea water by cyclic voltammetry on molybdenum (II)

Küçük Resim Yok

Tarih

2014

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

Elsevier Ltd

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

The electro-oxidation of H2S in Black Sea water to generate electricity was investigated. MoS2 exhibited catalytic activity toward the oxidation of H2S in artificial sea water. The catalytic activity of molybdenum sulfide was found to depend on the electrolyte pH and on the temperature. Cyclic voltammograms taken in the artificial sea water containing hydrogen sulfide at pH = 14 exhibited a peak at 500 mV related to the oxidation of HS-. Furthermore, the peak current of the MoS 2 electrode increased to 400 mA g-1 from 250 mA g -1 (approximately 1.6-fold) when the temperature was increased from 353 K to 363 K. © 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.

Açıklama

Anahtar Kelimeler

Black Sea water, Electro-oxidation, Hydrogen sulfide, Molybdenum sulfide catalyst

Kaynak

International Journal of Hydrogen Energy

WoS Q Değeri

Q1

Scopus Q Değeri

Q1

Cilt

39

Sayı

17

Künye