Selective extraction of iron(III) from aqueous nitrate solution in the presence of cobalt(II), copper(II) and nickel(II) ions using BiS(Delta(2)-2-imidazolinyl)-5,5 '-dioxime

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dc.contributor.authorTeke, M
dc.contributor.authorMercimek, B
dc.contributor.authorOzler, MA
dc.contributor.authorAyar, A
dc.date.accessioned2019-08-01T13:38:39Z
dc.date.available2019-08-01T13:38:39Z
dc.date.issued2004
dc.departmentNiğde ÖHÜ
dc.description.abstractThe feasibility of using bis(Delta(2)-2-imidazolinyl)-5,5'-dioxime (H2L) for the selective extraction of iron(III) from aqueous solutions was investigated by employing an solvent-extraction technique. The extraction of iron(III) from an aqueous nitrate solution in the presence of metal ions, such as cobalt(II), copper(II) and nickel(II), was carried out using H2L in binary and multicomponent mixtures. Iron(III) extraction has been studied as a function of the pH, equilibrium time and extractant concentration. From the extracted complex species in the organic phase, iron(III) was stripped with 2 M HNO3, and later determined using atomic-absorption spectrometry. The extraction was found to significantly depend on the aqueous solution pH. The extraction of iron(III) with H2L increases with the pH value, reaching a maximum in the zone of pH 2.0, remaining constant between 2 and 3.5 and subsequently decreasing. The quantitative extraction of iron(III) with 5 x 10(-3) M H2L in toluene is observed at pH 2.0. H2L was found to react with iron(III) to form ligand complex having a composition of 1:2 (Fe:H2L).
dc.identifier.doi10.2116/analsci.20.853
dc.identifier.endpage856
dc.identifier.issn0910-6340
dc.identifier.issue5
dc.identifier.pmid15171293
dc.identifier.scopus2-s2.0-3042575985
dc.identifier.scopusqualityQ3
dc.identifier.startpage853
dc.identifier.urihttps://dx.doi.org/10.2116/analsci.20.853
dc.identifier.urihttps://hdl.handle.net/11480/5662
dc.identifier.volume20
dc.identifier.wosWOS:000221413700018
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.institutionauthor[0-Belirlenecek]
dc.language.isoen
dc.publisherJAPAN SOC ANALYTICAL CHEMISTRY
dc.relation.ispartofANALYTICAL SCIENCES
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.titleSelective extraction of iron(III) from aqueous nitrate solution in the presence of cobalt(II), copper(II) and nickel(II) ions using BiS(Delta(2)-2-imidazolinyl)-5,5 '-dioxime
dc.typeArticle

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