Media effects on the optical properties of proton donor group containing azobenzene derivatives

Basit Öğe Kaydı
dc.contributor.authorOertel, Ulrich
dc.contributor.authorMart, Hasan
dc.contributor.authorKomber, Hartmut
dc.contributor.authorBoehme, Frank
dc.date.accessioned2019-08-01T13:38:39Z
dc.date.available2019-08-01T13:38:39Z
dc.date.issued2009
dc.departmentNiğde ÖHÜ
dc.description.abstractA series of hydroxy and carboxy group containing azobenzene compounds were synthesized and investigated by UV-vis and fluorescence spectroscopy. It could be shown that the ambient medium exerted a strong influence on the absorption behavior and the trans-cis isomerization behavior of the azo compounds. Especially in the case of hydroxy group functionalized azobenzenes, deprotonation with NaOH or a polymeric base changed the spectral behavior of the compounds remarkably. A strong bathochromic shift of the dyes' longest wavelength absorption band was observed. Furthermore, the influence of different solvents and different polymeric matrices on the trans-cis isomerization behavior of the azobenzenes was investigated. The results are discussed in terms of utilization of the azo dyes as probe molecules for interactions in polymer blends. (C) 2009 Elsevier B.V. All rights reserved.
dc.description.sponsorshipGerman Federal Ministry for Education, Science, Research and Technology [TUR 04/008]; Scientific and Technical Research Council of Turkey
dc.description.sponsorshipThe authors acknowledge the financial support of the fund for international cooperation of the German Federal Ministry for Education, Science, Research and Technology (project No. TUR 04/008) and of the Scientific and Technical Research Council of Turkey (TUBITAK).
dc.identifier.doi10.1016/j.optmat.2009.06.010
dc.identifier.endpage61
dc.identifier.issn0925-3467
dc.identifier.issn1873-1252
dc.identifier.issue1
dc.identifier.scopus2-s2.0-70349998758
dc.identifier.scopusqualityQ1
dc.identifier.startpage54
dc.identifier.urihttps://dx.doi.org/10.1016/j.optmat.2009.06.010
dc.identifier.urihttps://hdl.handle.net/11480/5000
dc.identifier.volume32
dc.identifier.wosWOS:000271888500012
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthor[0-Belirlenecek]
dc.language.isoen
dc.publisherELSEVIER SCIENCE BV
dc.relation.ispartofOPTICAL MATERIALS
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectTrans-cis isomerization
dc.subjectAzo polymers
dc.subjectHost-guest systems
dc.subjectPhotochemistry
dc.subjectPolyamidine
dc.subjectPMMA
dc.subjectUV-vis spectroscopy
dc.titleMedia effects on the optical properties of proton donor group containing azobenzene derivatives
dc.typeArticle

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu