Thermal decomposition kinetics of anilino-p-chlorophenylglyoxime complexes of cobalt (II), nickel (II) and copper (II)

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dc.authorid0000-0003-0046-9442
dc.authorid0000-0002-6678-1036
dc.contributor.authorArslan, H
dc.contributor.authorKulcu, N
dc.contributor.authorPekacar, AI
dc.date.accessioned2019-08-01T13:38:39Z
dc.date.available2019-08-01T13:38:39Z
dc.date.issued2003
dc.departmentNiğde ÖHÜ
dc.description.abstractThe Co(II), Ni(II) and Cu(II) complexes of anilino-p-chlorophenylglyoxime were synthesised. The thermal behaviour of all complexes was studied by DTA and TG. It was found that pyrolytic decomposition occurs with melting in metal complexes and that metal oxides remain as final products of the metal complexes. A GC-MS combined system was used to identify the products during pyrolytic decomposition. The pyrolytic end products were identified by x-ray powder diffraction. The orders, n, the activation energies, E*, the pre-exponential factors, A, and the entropies, DeltaS*, of thermal decomposition reactions were derived from thermogravimetric and differential thermogravimetric curves. The, kinetic analysis of the thermogravimetric data was performed by using the Coats-Redfern and Horowitz-Metzger methods.
dc.identifier.endpage63
dc.identifier.issn1010-7614
dc.identifier.issue1
dc.identifier.scopus2-s2.0-0037223511
dc.identifier.scopusqualityN/A
dc.identifier.startpage55
dc.identifier.urihttps://hdl.handle.net/11480/5724
dc.identifier.volume27
dc.identifier.wosWOS:000181586900009
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthor[0-Belirlenecek]
dc.language.isoen
dc.publisherSCIENTIFIC TECHNICAL RESEARCH COUNCIL TURKEY
dc.relation.ispartofTURKISH JOURNAL OF CHEMISTRY
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectanilino-p-chlorophenylglyoxime
dc.subjectCu(II)-
dc.subjectNi(II)- and Co(II)-complexes
dc.subjectthermal behaviour
dc.subjectthermal decomposition kinetic
dc.subjectpyrolysis
dc.subjectDTA/TG/DTG
dc.titleThermal decomposition kinetics of anilino-p-chlorophenylglyoxime complexes of cobalt (II), nickel (II) and copper (II)
dc.typeArticle

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