AMINOPHOSPHINES DERIVED FROM 1-AMINO-4-METHYLPIPERAZINE: SYNTHESIS, OXIDATION AND COMPLEXATION REACTIONS

Küçük Resim Yok

Tarih

2012

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

TAYLOR & FRANCIS LTD

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

Functionalized mono(amino)phosphines of the type Ph2PNHR (1) and bis (amino) phosphine of the type PhP(NHR)(2) (2) have been synthesized by treating Ph2PCl or PhPCl2 with 1-amino-4-methylpiperazine. Ligands react with aqueous hydrogen peroxide, elemental sulfur, or selenium to give the corresponding chalcogenides in good yields. The molybdenum complexes of the aminophosphines have been obtained. All of the new compounds were characterized by IR, H-1, and P-31-NMR spectroscopy and elemental analysis.

Açıklama

Anahtar Kelimeler

Mono(amino)phosphine, bis(amino)phosphine, aminophosphine chalcogenides

Kaynak

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS

WoS Q Değeri

Q4

Scopus Q Değeri

Q4

Cilt

187

Sayı

8

Künye