Preparation of heterotricyclic chlorides via intramolecular Diels-Alder reaction of furans
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Date
2007
Authors
Journal Title
Journal ISSN
Volume Title
Publisher
ASIAN JOURNAL OF CHEMISTRY
Access Rights
info:eu-repo/semantics/closedAccess
Abstract
A variety of key precursors to the intramolecular Diels-Alder (IMDA) reaction of furan diene have been prepared via facile alkylation. Subsequently, rigid heterotricyclic chlorides 5a-e possessing oxygen, nitrogen and sulfur have been synthesized by employing a thermal IMDA reactions. Use of bulky protecting group on nitrogen 5a-b, such as t-butoxy group, can be utilized to encourage cycloaddition reactions that otherwise does not proceed.
Description
Keywords
intramolecular Diels-Alder, cycloaddition, furfurylchloroalkenes
Journal or Series
ASIAN JOURNAL OF CHEMISTRY
WoS Q Value
Q4
Scopus Q Value
Q4
Volume
19
Issue
4
