Interactional study of a polymeric organotin complex in micellar media

Basit Öğe Kaydı
dc.authoridNoor, Sadia/0000-0002-4709-0029
dc.authoridShabbir, Saima/0000-0003-3482-3040
dc.authoridTAJ, Dr. Muhammad Babar/0000-0001-5343-6893
dc.authoridSelamoglu, Zeliha/0000-0001-9056-6435
dc.contributor.authorNoor, Sadia
dc.contributor.authorRaheel, Ahmad
dc.contributor.authorTaj, Muhammad Babar
dc.contributor.authorShabbir, Saima
dc.contributor.authorAhmad, Raja Hammad
dc.contributor.authorSelamoglu, Zeliha
dc.date.accessioned2024-11-07T13:35:18Z
dc.date.available2024-11-07T13:35:18Z
dc.date.issued2023
dc.departmentNiğde Ömer Halisdemir Üniversitesi
dc.description.abstractIn this manuscript, a study on interactions of a polymeric derivative of Tributyltin(IV) with [(2-Methylpropanoyl)amino]propanoic acid (TMP) in micellar media is presented. The study was conducted using two surfactants viz. Sodium 2-ethylhexylsulphate (SES) and Cetyltrimethylammonium bromide (CTAB). The solubilization parameters in terms of partition constant (K-c), partition coefficient (K-x), binding constant (K-b), Gibb's free energy of partition (Delta G(p)), and binding (Delta G(b)) were investigated by UV-Visible spectrophotometer. The estimation of micellization thermodynamics including entropy (Delta S-m), enthalpy (Delta H-m), and Gibb's free energy (Delta G(m)) were determined conductometrically. The compound showed more interaction with the cationic surfactant as compared to anionic participating surfactant due to comparative electrostatic interactions. The partition coefficient (K-x) in the micellar media of CTAB was significantly higher (4.22 x 10(7)) than SES media (1.33 x 10(5)). The Gibb's free energies of partition. Binding and micellization were higher in CTAB as compared to SES.
dc.identifier.doi10.1080/01932691.2021.1948421
dc.identifier.endpage358
dc.identifier.issn0193-2691
dc.identifier.issn1532-2351
dc.identifier.issue2
dc.identifier.scopus2-s2.0-85110813656
dc.identifier.scopusqualityQ3
dc.identifier.startpage349
dc.identifier.urihttps://doi.org/10.1080/01932691.2021.1948421
dc.identifier.urihttps://hdl.handle.net/11480/16439
dc.identifier.volume44
dc.identifier.wosWOS:000673325200001
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherTaylor & Francis Inc
dc.relation.ispartofJournal of Dispersion Science and Technology
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241106
dc.subject[(2-Methylpropanoyl)amino] propanoic acid
dc.subjectelectrical conductivity
dc.subjectmicellar
dc.subjectinteraction
dc.subjectUV-Vis spectroscopy
dc.subjecttributyltin(IV) derivative
dc.titleInteractional study of a polymeric organotin complex in micellar media
dc.typeArticle

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu