Effect of reduced graphene oxide addition on cathode functional layer performance in solid oxide fuel cells
Küçük Resim Yok
Tarih
2023
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Pergamon-Elsevier Science Ltd
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Solid oxide fuel cells (SOFCs) operating at high temperatures are highly efficient electrochemical devices since they convert the chemical energy of a fuel directly into heat and electrical energy. The electrochemical performance of an SOFC is significantly influenced by the materials and microstructure of the electrodes since the electrochemical reactions in SOFCs take place at three/triple phase boundaries (TPBs) within the electrodes. In this study, graphene in the form of reduced graphene oxide (rGO) is added to cathode functional layer (CFL) to improve the cell performance by utilizing the high electrical properties of graphene. Various cells are prepared by varying the rGO content in CFL slurry (1-5 wt %), the number of screen printing (1-3) and the cathode sintering temperature (900-1100 degrees C). The electrochemical behavior of the cells is evaluated by electrochemical performance and impedance tests. It is observed that there is a similar to 26% increase in the peak performance of the cell coated with single layer CFL having 1 wt % graphene and 1050 degrees C sintering temperature, compared to that of the reference cell. (c) 2022 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
Açıklama
Anahtar Kelimeler
Solid oxide fuel cell, Reduced graphene oxide, Cathode functional layer, Electrochemical performance
Kaynak
International Journal of Hydrogen Energy
WoS Q Değeri
Q1
Scopus Q Değeri
Q1
Cilt
48
Sayı
60