Synthesis and photoluminescence characteristics of a novel Eu and Tb doped Li2MoO4 phosphor

dc.authoridKaynar, Umit H./0000-0002-3321-0341
dc.authoridCoban, Mustafa Burak/0000-0003-3488-5284
dc.authoridAYVACIKLI, Mehmet/0000-0002-7278-046X
dc.authoridOglakci, Mehmet/0000-0003-1096-5087
dc.contributor.authorSouadi, G.
dc.contributor.authorKaynar, U. H.
dc.contributor.authorAyvacikli, M.
dc.contributor.authorCoban, M. B.
dc.contributor.authorOglakci, M.
dc.contributor.authorCanimoglu, A.
dc.contributor.authorCan, N.
dc.date.accessioned2024-11-07T13:35:14Z
dc.date.available2024-11-07T13:35:14Z
dc.date.issued2021
dc.departmentNiğde Ömer Halisdemir Üniversitesi
dc.description.abstractLi2MoO4:x Eu3+ and Li2MoO4:xTb(3+) phosphors, where x = 0.5, 1, 2, 3, 5 and 7 wt%, were synthesized through a gel-combustion method. The XRD data reveals that Eu3+ and Tb3+ doped Li2MoO4 phosphors exhibit a Rhombohedral structure belonging to the space group R3 which matched well with the standard JCPDS files (No.0120763). We present photoluminescence (PL) spectra from Eu and Tb doped Li2MoO4 under 349 nm Nd:YLF pulses laser excitation over the temperature range of 10-300 K. Undoped Li2MoO4 shows a wide broad band around 600 nm because of the intrinsic PL emission of tetrahedral of MoO42- which was in good agreement with previous findings. Under the excitation of 394 nm, the as-synthesized phosphors exhibited sharp and strong intensity PL emission signals in the red (612 nm, D-5(0) -> F-7(2) transition) and green (544 nm, D-5(4) -> F-7(5) transition), respectively. The critical doping concentration of Eu3+ and Tb3+ ions in the Li2MoO4 were estimated to be 2 wt%. The concentration quenching phenomena were discussed, and the critical distances for energy transfer have also been evaluated by the concentration quenching.
dc.identifier.doi10.1016/j.apradiso.2021.109820
dc.identifier.issn0969-8043
dc.identifier.issn1872-9800
dc.identifier.pmid34126367
dc.identifier.scopus2-s2.0-85107694712
dc.identifier.scopusqualityQ3
dc.identifier.urihttps://doi.org/10.1016/j.apradiso.2021.109820
dc.identifier.urihttps://hdl.handle.net/11480/16393
dc.identifier.volume175
dc.identifier.wosWOS:000662833000013
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherPergamon-Elsevier Science Ltd
dc.relation.ispartofApplied Radiation and Isotopes
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241106
dc.subjectLi2MoO4
dc.subjectGel-combustion method
dc.subjectPhotoluminescence
dc.subjectConcentration quenching
dc.subjectCritical distance
dc.titleSynthesis and photoluminescence characteristics of a novel Eu and Tb doped Li2MoO4 phosphor
dc.typeArticle

Dosyalar