Oxidative polycondensation reaction

Küçük Resim Yok

Tarih

2006

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

VSP BV

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

In the last few years, some monomers such as phenols, anilines, pyridines, naphtols, Schiff bases and azo phenols have been subjected to oxidative polycondensation (OP) using NaOCl, H2O2 and air O-2 as the oxidants in aqueous alkaline or aqueous acidic medium. This resulted in oligomers with potential useful properties. The major reason behind these investigations was the economic and environmentally benign reaction process of OP. Therefore, this review diccusses OP and the obtained oligomers in detail. Additionally, chemical structures, physical properties, UV-Vis, FT-IR, H-1- and C-13-NMR analyses, thermal properties and coupling mechanism of all oligomers synthesized via OP are discussed and compared to those of polymers prepared by other oxidative methods. The probable potential applications of the obtained polymers and oligomers, such as antistatic and semi-conductivity, fluorescent, photoresist, opto-electronic, electrochromic, antimicrobial and photoresponsive properties, are also discussed in the last section.

Açıklama

Anahtar Kelimeler

oxidative polymerization, oxidative polycondensation, Schiff base polymers, polyphenols, azo polymers, green chemistry

Kaynak

DESIGNED MONOMERS AND POLYMERS

WoS Q Değeri

Q3

Scopus Q Değeri

Q2

Cilt

9

Sayı

6

Künye