Oxidative polycondensation reaction
Küçük Resim Yok
Tarih
2006
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
VSP BV
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
In the last few years, some monomers such as phenols, anilines, pyridines, naphtols, Schiff bases and azo phenols have been subjected to oxidative polycondensation (OP) using NaOCl, H2O2 and air O-2 as the oxidants in aqueous alkaline or aqueous acidic medium. This resulted in oligomers with potential useful properties. The major reason behind these investigations was the economic and environmentally benign reaction process of OP. Therefore, this review diccusses OP and the obtained oligomers in detail. Additionally, chemical structures, physical properties, UV-Vis, FT-IR, H-1- and C-13-NMR analyses, thermal properties and coupling mechanism of all oligomers synthesized via OP are discussed and compared to those of polymers prepared by other oxidative methods. The probable potential applications of the obtained polymers and oligomers, such as antistatic and semi-conductivity, fluorescent, photoresist, opto-electronic, electrochromic, antimicrobial and photoresponsive properties, are also discussed in the last section.
Açıklama
Anahtar Kelimeler
oxidative polymerization, oxidative polycondensation, Schiff base polymers, polyphenols, azo polymers, green chemistry
Kaynak
DESIGNED MONOMERS AND POLYMERS
WoS Q Değeri
Q3
Scopus Q Değeri
Q2
Cilt
9
Sayı
6
