Reactive Extraction as an Intensifying Approach for the Recovery of Organic Acids from Aqueous Solution: A Comprehensive Review on Experimental and Theoretical Studies

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dc.authoridWasewar, Kailas/0000-0001-7453-6308
dc.authoridKumar, Sushil/0000-0001-7114-4579
dc.contributor.authorKumar, Sushil
dc.contributor.authorPandey, Shitanshu
dc.contributor.authorWasewar, Kailas L.
dc.contributor.authorAk, Namik
dc.contributor.authorUslu, Hasan
dc.date.accessioned2024-11-07T13:34:42Z
dc.date.available2024-11-07T13:34:42Z
dc.date.issued2021
dc.departmentNiğde Ömer Halisdemir Üniversitesi
dc.description.abstractOrganic acids are important targeted chemicals worldwide due to their variety of functionalities in various fields. Organic acids can be produced through chemical processes of fossil raw materials as well as by the microbial fermentation of natural occurring biomass. Because of growing environmental concern, the production pathways are shifting toward biobased green technologies. The primary challenge in the biological synthesis of organic acids is the downstream recovery of the main products from the fermentation broth/aqueous stream. Among the various techniques for the downstream processing, reactive (liquid) extraction is deemed as a great opportunity for this purpose. It is an energy-saving process with flexibility in production scale and a high degree of separation and selectivity. In this review, starting with highlighting the bioproduction and various alternatives available for the recovery of organic acids from aqueous solution, the reactive extraction, an intensified approach is described in detail. The influence of reactive extraction parameters, insights of equilibrium and kinetic mechanisms, and thermodynamic aspects are discussed and analyzed. Different theoretical models for process optimization, determination of equilibrium, kinetic, and thermodynamic parameters, and quantification of solvents' effect are also explained in detail. This paper also highlights recent experimental and theoretical studies for the recovery of different organic acids using amine, phosphorus, and ionic liquid based extractants from fermentation broth/industrial waste streams. In addition, industrial development on the recovery of organic acids using the reactive extraction approach is also described.
dc.identifier.doi10.1021/acs.jced.0c00405
dc.identifier.endpage1573
dc.identifier.issn0021-9568
dc.identifier.issn1520-5134
dc.identifier.issue4
dc.identifier.scopus2-s2.0-85103477597
dc.identifier.scopusqualityQ2
dc.identifier.startpage1557
dc.identifier.urihttps://doi.org/10.1021/acs.jced.0c00405
dc.identifier.urihttps://hdl.handle.net/11480/16126
dc.identifier.volume66
dc.identifier.wosWOS:000639039300002
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherAmer Chemical Soc
dc.relation.ispartofJournal of Chemical and Engineering Data
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241106
dc.subjectTri-N-Octylamine
dc.subjectResponse-Surface Methodology
dc.subjectLiquid-Liquid-Extraction
dc.subjectLactic-Acid
dc.subjectSuccinic Acid
dc.subjectCitric-Acid
dc.subjectAmberlite La-2
dc.subjectFermentation Broth
dc.subjectCarboxylic-Acids
dc.subjectButyl Phosphate
dc.titleReactive Extraction as an Intensifying Approach for the Recovery of Organic Acids from Aqueous Solution: A Comprehensive Review on Experimental and Theoretical Studies
dc.typeReview Article

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