Synthesis of New Type of Macrocyclic Lactones Functionalized with Different Groups and Investigation of Their Metal Binding Abilities
Küçük Resim Yok
Tarih
2009
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
POLISH CHEMICAL SOC
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
New type of macrocyclic lactones functionalized with different groups were synthesized by reaction of the dihydroxy compounds such as 5a-d with suitable glycolyl chloride such as tri, tetra dicarboxylic acid dichloride derivatives. Their metal complexes with NaClO4 center dot H2O, KClO4 and Ba(ClO4)(2)center dot H2O were studied. Furthermore, their metal-picrate extraction studies with metal salts such as Na+, K+, Cu2+, Ni2+ and Hg2+ from aqueous phase to organic phase were attempted. All the structures of the ligands and complexes were confirmed by H-I-, C-13-NMR, IR, UV-Vis, MS and elemental analyses methods.
Açıklama
Anahtar Kelimeler
macrocyclic ligand, lactone, metal-picrate extraction, Schotten-Baumann reaction
Kaynak
POLISH JOURNAL OF CHEMISTRY
WoS Q Değeri
Q4
Scopus Q Değeri
Cilt
83
Sayı
3
