Synthesis and characterization of conducting copolymer of Trans-1-(4-methyl-3'-thienyl)-2-(ferrocenyl)ethene with EDOT

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dc.authorid0000-0002-7324-0385
dc.contributor.authorTurac, Ersen
dc.contributor.authorSahmetlioglu, Ertugrul
dc.contributor.authorDemircan, Aydin
dc.contributor.authorToppare, Levent
dc.date.accessioned2019-08-01T13:38:39Z
dc.date.available2019-08-01T13:38:39Z
dc.date.issued2012
dc.departmentNiğde ÖHÜ
dc.description.abstractFerrocene-substituted conducting polymer namely poly(trans-1-(4-methyl-3'-thienyl)-2-(ferrocenyl)ethene-co-3,4-ethylenedioxythiophene) [P(MTFE-co-EDOT)] was synthesized and its electrochromic properties were studied. Monomer, MTFE, was obtained using 2-(ferrocenyl)ethene and 3-methyl-4-bromothiophene. The structure of monomer was determined via Fourier transform infrared spectroscopy (FTIR), 1H-NMR, and 13C-NMR techniques. The copolymer was synthesized using this monomer and EDOT. The resulting copolymer P(MTFE-co-EDOT) was characterized by cyclic voltammetry, FTIR, scanning electron microscopy, atomic force microscopy, and UVvis spectroscopy. The conductivity measurements of copolymer and PEDOT were accomplished by the four-probe technique. Although poly(trans-1-(4-methyl-3'-thienyl)-2-(ferrocenyl)ethene) [P(MTFE)] reveals no electrochromic activity, its copolymer with EDOT has two different colors (violet and gray). Band gap (Eg) and ?max of P(MTFE-co-EDOT) were determined. (c) 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012
dc.identifier.doi10.1002/app.36948
dc.identifier.endpage814
dc.identifier.issn0021-8995
dc.identifier.issue3
dc.identifier.scopus2-s2.0-84864672013
dc.identifier.scopusqualityQ2
dc.identifier.startpage808
dc.identifier.urihttps://dx.doi.org/10.1002/app.36948
dc.identifier.urihttps://hdl.handle.net/11480/4519
dc.identifier.volume126
dc.identifier.wosWOS:000307054700003
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthor[0-Belirlenecek]
dc.language.isoen
dc.publisherWILEY-BLACKWELL
dc.relation.ispartofJOURNAL OF APPLIED POLYMER SCIENCE
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectferrocene
dc.subjectEDOT
dc.subjectAFM
dc.subjectcopolymerization
dc.titleSynthesis and characterization of conducting copolymer of Trans-1-(4-methyl-3'-thienyl)-2-(ferrocenyl)ethene with EDOT
dc.typeArticle

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