Synthesis and properties of novel Schiff base oligomers based on oligo-4-hydroxybenzaldehyde

Küçük Resim Yok

Tarih

2004

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

JOHN WILEY & SONS INC

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

Condensation of oligo-4-hydroxybenzaldehyde with aniline, 2-chloroaniline, 2-aminophenol, 2-aminotoluene, 4-aminotoluene, and 4-nitroaniline gave the corresponding Schiff base oligomers (OFAP, OKAP, OHAP, OOAP, OTAP, and ONAP, respectively). The products were characterized by H-1 NMR, Fourier transform infrared, ultraviolet-visible, and elemental analyses. The number-average molecular weight, mass-average molecular weight, and polydispersity index (PDI) values of the Schiff base oligomers were determined. Thermogravimetric analysis was used to compare the thermal stability of the oligomers, which showed the Schiff base oligomers to be resistant to thermooxidative decomposition. Weight loss of 5% and 50% occurred at temperatures of 122 and 475 degreesC; for OFAP, at 118 and 453 degreesC; for OKAP, at 182 and 491 degreesC; for OHAP, at 150 and 452 degreesC; for OOAP, at 132 and 401 degreesC; for OTAP, and at 193 and 414 degreesC for ONAP. (C) 2004 Wiley Periodicals, Inc.

Açıklama

Anahtar Kelimeler

oligo-4-hydroxybenzaldehyde, Schiff base oligomers, oxidative polycondensation

Kaynak

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

WoS Q Değeri

Q1

Scopus Q Değeri

N/A

Cilt

42

Sayı

5

Künye