A new soluble Schiff base polymer with a double azomethine group synthesized by oxidative polycondensation

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dc.authorid0000-0002-7697-3613
dc.contributor.authorOezbuelbuel, A.
dc.contributor.authorMart, H.
dc.contributor.authorTuncel, M.
dc.contributor.authorSerin, S.
dc.date.accessioned2019-08-01T13:38:39Z
dc.date.available2019-08-01T13:38:39Z
dc.date.issued2006
dc.departmentNiğde ÖHÜ
dc.description.abstractA Schiff base monomer was synthesized by the condensation reaction between salicylaldehyde and ethylenediamine. The Schiff base polymer, with a double azomethine group, was prepared by oxidative polycondensation (OP) reaction of monomer in aqueous alkaline medium with NaOCl as an oxidant at 90 degrees C. The monomer and polymer were characterized by UV-Vis, FT-IR, H-1-and C-13-NMR spectroscopic studies, which revealed that the polymer synthesized by OP is composed of oxyphenylene (55%) and phenylene (45%) units. The polymer was soluble in aqueous alkaline, THF, DMF and DMSO. The thermal properties of monomer and polymer were evaluated by differential thermal analysis (DTA) and thermogravimetric (TG) analyses. According to TG, the 5% and 50% weight loss temperatures of the polymer were 200 degrees C and 800 degrees C, respectively.
dc.identifier.doi10.1163/156855506776382655
dc.identifier.endpage179
dc.identifier.issn1385-772X
dc.identifier.issn1568-5551
dc.identifier.issue2
dc.identifier.scopus2-s2.0-33744513098
dc.identifier.scopusqualityQ2
dc.identifier.startpage169
dc.identifier.urihttps://dx.doi.org/10.1163/156855506776382655
dc.identifier.urihttps://hdl.handle.net/11480/5547
dc.identifier.volume9
dc.identifier.wosWOS:000237921600005
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthor[0-Belirlenecek]
dc.language.isoen
dc.publisherTAYLOR & FRANCIS LTD
dc.relation.ispartofDESIGNED MONOMERS AND POLYMERS
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectschiff base polymer
dc.subjectoxidative polymerization
dc.subjectsoluble polymer
dc.titleA new soluble Schiff base polymer with a double azomethine group synthesized by oxidative polycondensation
dc.typeArticle

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