Synthesis and trivalent lanthanide ion complexation studies of new macrocyclic receptors based lactam ionophores

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dc.contributor.authorGullu, Fadime
dc.contributor.authorBayrakci, Mevlut
dc.contributor.authorKursunlu, Ahmed Nuri
dc.contributor.authorYigiter, Sengul
dc.contributor.authorErtul, Seref
dc.date.accessioned2019-08-01T13:38:39Z
dc.date.available2019-08-01T13:38:39Z
dc.date.issued2014
dc.departmentNiğde ÖHÜ
dc.description.abstractThis study is the first report on the design, synthesis and photophysical properties of three new macrocyclic receptors based receptors containing two amide bridges. Their binding properties towards trivalent lanthanide ions such as La3+, Gd3+, Tb3+, Dy3+, Er3+ and Yb3+ were investigated by using spectroscopic techniques. With respect to emission intensity changes upon trivalent lanthanide ion complexation, macrocyclic receptors based lactam ionophores showed higher selectivity towards Yb3+ and/or Er3+ ion over other ions. Presence of proximal two amide groups in macrocyclic lactam receptors having different cavity size were observed to play an important role in exhibiting its lanthanide ion binding.
dc.description.sponsorshipSelcuk University; Nigde University Research Foundation (BAP)
dc.description.sponsorshipThe authors gratefully would like to thank Selcuk University and Nigde University Research Foundation (BAP) for financial support.
dc.identifier.doi10.1007/s10847-014-0403-9
dc.identifier.endpage312
dc.identifier.issn1388-3127
dc.identifier.issn1573-1111
dc.identifier.issue45385
dc.identifier.scopus2-s2.0-84896058617
dc.identifier.scopusqualityQ3
dc.identifier.startpage303
dc.identifier.urihttps://dx.doi.org/10.1007/s10847-014-0403-9
dc.identifier.urihttps://hdl.handle.net/11480/4100
dc.identifier.volume80
dc.identifier.wosWOS:000343603000015
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthor[0-Belirlenecek]
dc.language.isoen
dc.publisherSPRINGER
dc.relation.ispartofJOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectLactam
dc.subjectMolecular recognition
dc.subjectYtterbium
dc.subjectErbium
dc.subjectChemosensor
dc.subjectPhotoswitch
dc.titleSynthesis and trivalent lanthanide ion complexation studies of new macrocyclic receptors based lactam ionophores
dc.typeArticle

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