Thermal studies of p-toluidino-p-chlorophenylglyoxime and of some corresponding Ni(II), Cu(II) and Co(II) complexes
Küçük Resim Yok
Tarih
1999
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
ELSEVIER SCIENCE BV
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
The thermal behaviour of p-toluidino-p-chlorophenylglyoxime (pTpCPG) and its Cu(II), NI(TI), and Co(LI) complexes have been studied by DTA and TG. It was found that pyrolytic decomposition undergoes with melting in both Ligand and its metal complexes and metal oxides remained as end products of the metal complexes. The ligand decomposes in two stages through two different mechanisms and the metal chelates undergo decomposition in three stages. GC-MS combined system was used to identify the products during pyrolytic decompositions. The pyrolytic end products were identified by X-ray powder diffraction. (C) 1999 Elsevier Science B.V. All rights reserved.
Açıklama
Anahtar Kelimeler
p-toluidino-p-chlorophenylglyoxime, Cu(II)-, Ni(II) and Co(II)-complexes, thermal behaviour, pyrolysis, DTA/TG/DTG
Kaynak
THERMOCHIMICA ACTA
WoS Q Değeri
Q3
Scopus Q Değeri
Q2
Cilt
329
Sayı
1
