Studies on Dual Phase Ceria-based Composites in Electrochemistry

dc.contributor.authorZhu, Bin
dc.contributor.authorMat, Mahmut D.
dc.date.accessioned2019-08-01T13:38:39Z
dc.date.available2019-08-01T13:38:39Z
dc.date.issued2006
dc.departmentNiğde ÖHÜ
dc.description.abstractThe ceria-based dual-phase composites have been recently developed as functional electrolytes successful for intermediate and low temperature solid oxide fuel cell applications. These composite materials showed many unique advantages over the conventional single-phase electrolytes, such as superionic conduction in two-phase interfaces, dual proton and oxygen ion conduction resulting in extremely high ion conductivity and high current outputs in fuel cell and other applications, e. g. electrolysis. Interfacial superionic conduction is a characteristic for high conducting dual-phase composites. The composite approach can combine or integrate multi-ion functions, typically, dual H(+) and O(2-)conduction together to enhance the material conductivity and device performance. Dual or hybrid H+ and O(2-)conduction is based on a consideration that both proton (H+) and oxygen ion (O(2-)) are the fuel cell source ions. Proton conduction is important for LTSOFCs since it can be activated easier than oxygen ions in the low temperature (LT, 300-600 degrees C) region. The superionic conduction, dual phase proton and oxygen ion transport make significant conduction and electrical contributions for electrochemical devices. This paper makes a review on these recent studies.
dc.description.sponsorshipCarl Tryggers Stiftelse for Vetenskap Forskning (CTS); Dalian Maritime University; Turkish National Science Foundation (TUBITAK)
dc.description.sponsorshipThis work is supported by Carl Tryggers Stiftelse for Vetenskap Forskning (CTS) and also Dalian Maritime University lecturing professor project. Partial financial support of Turkish National Science Foundation (TUBITAK) for cooperation between KTH and Nigde University is acknowledged.
dc.identifier.endpage402
dc.identifier.issn1452-3981
dc.identifier.issue8
dc.identifier.scopus2-s2.0-36349018634
dc.identifier.scopusqualityQ3
dc.identifier.startpage383
dc.identifier.urihttps://hdl.handle.net/11480/5462
dc.identifier.volume1
dc.identifier.wosWOS:000208126900001
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthor[0-Belirlenecek]
dc.language.isoen
dc.publisherELECTROCHEMICAL SCIENCE GROUP
dc.relation.ispartofINTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
dc.relation.publicationcategoryDiğer
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectfuel cell
dc.subjectceria-composite electrolytes
dc.subjectproton and oxygen ion conduction
dc.titleStudies on Dual Phase Ceria-based Composites in Electrochemistry
dc.typeReview Article

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