THE SYNTHESIS AND NI(II), CO(II), CU(II), ZN(II), CD(II) AND UO2(VI) COMPLEXES OF N,N'-BIS(2-TOLYL)DIAMINOGLYOXIME AND N,N'-BIS(4-TOLYL)DIAMINOGLYOXIME

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dc.contributor.authorMERCIMEK, B
dc.contributor.authorOZCAN, E
dc.contributor.authorPEKACAR, AI
dc.date.accessioned2019-08-01T13:38:39Z
dc.date.available2019-08-01T13:38:39Z
dc.date.issued1995
dc.departmentNiğde ÖHÜ
dc.description.abstractN,N'-Bis(2-toyl)diaminoglyoxime (L(1)H(2)) and N,N'-bis(4-tolyl)diaminoglyoxime (L(2)H(2)) have been prepared from anti-dichloroglyoxime with o-toluidine and p-toluidine in ethanol. The complexes of these vic-dioximes with Ni(II), Co(II), Cu(II), Zn(II), Cd(II) and UO2(VI) metal ions have been investigated. The nickel(II), cobalt(ll) and copper(ll) complexes of the ligands have a metal-ligand ratio of 1:2 and the ligand oo-ordinates through the N atoms, as do most of the vic-dioximes. [Zn(LH)Cl(O-2)] and [Cd(LH)CI(H2O)] (LH(2) = L(1)H(2) or L(2)H(2)) form six-membered chelate rings and co-ordinate through N and O atoms. LH(2) reacts with UO2(CH3COO)(2) . 2H(2)O to give binuclear complexes with a metal-ligand ratio of 1:1. Their structures were identified by elemental analyses and H-1 NMR, IR, UV-visible spectroscopy, respectively.
dc.identifier.doi10.1080/15533179508218291
dc.identifier.endpage1579
dc.identifier.issn0094-5714
dc.identifier.issue9
dc.identifier.scopus2-s2.0-21844510088
dc.identifier.scopusqualityN/A
dc.identifier.startpage1571
dc.identifier.urihttps://dx.doi.org/10.1080/15533179508218291
dc.identifier.urihttps://hdl.handle.net/11480/5839
dc.identifier.volume25
dc.identifier.wosWOS:A1995TA83700013
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthor[0-Belirlenecek]
dc.language.isoen
dc.publisherMARCEL DEKKER INC
dc.relation.ispartofSYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.titleTHE SYNTHESIS AND NI(II), CO(II), CU(II), ZN(II), CD(II) AND UO2(VI) COMPLEXES OF N,N'-BIS(2-TOLYL)DIAMINOGLYOXIME AND N,N'-BIS(4-TOLYL)DIAMINOGLYOXIME
dc.typeArticle

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