3D printed anode electrodes for microbial electrolysis cells

Basit Öğe Kaydı
dc.authoridBAS, FURKAN/0000-0002-1312-6871
dc.authoridKAYA, Mehmet Fatih/0000-0002-2444-0583
dc.contributor.authorBas, Furkan
dc.contributor.authorKaya, Mehmet Fatih
dc.date.accessioned2024-11-07T13:31:22Z
dc.date.available2024-11-07T13:31:22Z
dc.date.issued2022
dc.departmentNiğde Ömer Halisdemir Üniversitesi
dc.description.abstractMicrobial electrolysis cells are used to produce high purity hydrogen from organic wastes. Electrodes are one of the most important components of microbial electrolysis cells because they may directly affect the system performance. Moreover, these electrodes are costly and may negatively affect electrolysis performance by giving chemical reactions with organic wastes. This study uses cheese whey wastewater as electrolyte, and a two chambered microbial electrolysis cell with novel different shaped 3D printed anode electrodes. To improve mass transfer inside the cell, 3D designed, and printed electrodes are used in different geometries (rod, 1-cycled spiral, 2-cycled spiral, 3-cycled spiral, and 4-cycled spiral) by using cupper-based Electrifi filament. Electrochemical performance of the electrodes is observed by cyclic voltammetry, linear sweep voltammetry, and electrochemical impedance spectroscopy analysis. As a result, it is observed that the organic content of waste and electrode geometry directly affects the microbial electrolysis performance and hydrogen production. In the electrochemical analysis, 1-cycled spiral geometry has up to 2.6-fold higher current density in linear sweep voltammetry analysis. In addition, in the hydrogen production measurements, 1-cycled spiral geometry is 5-fold faster than other electrodes. It is observed that spiral shape of the electrodes improves the contact region between the electrode and electrolyte interface, and the charge transfer performance.
dc.description.sponsorshipScientific and Technological Research Council of Turkey [1649B022101341]; Scientific Research Projects Unit Erciyes University [FYL-2020-10620]
dc.description.sponsorshipThe authors would like to thank the following for funding and supporting the project: The Scientific and Technological Research Council of Turkey (TUEBI?TAK, contract number 1649B022101341) and The Scientific Research Projects Unit Erciyes University, under contract number FYL-2020-10620. Authors also would like to thanks to Erciyes Univer-sity Agricultural Research and Application Center (ERUTAM) for their help for providing cheese whey waste samples.
dc.identifier.doi10.1016/j.fuel.2022.123560
dc.identifier.issn0016-2361
dc.identifier.issn1873-7153
dc.identifier.scopus2-s2.0-85124470941
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1016/j.fuel.2022.123560
dc.identifier.urihttps://hdl.handle.net/11480/14810
dc.identifier.volume317
dc.identifier.wosWOS:000783251200003
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Sci Ltd
dc.relation.ispartofFuel
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241106
dc.subject3D printed electrodes
dc.subjectCheese whey wastewater
dc.subjectCopper-based materials
dc.subjectHydrogen
dc.subjectMicrobial electrolysis cell
dc.subjectHydrogen production
dc.title3D printed anode electrodes for microbial electrolysis cells
dc.typeArticle

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