Synthesis, Characterization and Optoelectrochemical Properties of Poly(2,5-di(thiophen-2-yl)-1-(4-(thiophen-3-yl)phenyl)-1H-pyrrole-co-EDOT)

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dc.authorid0000-0002-7324-0385
dc.contributor.authorTurac, Ersen
dc.contributor.authorSahmetlioglu, Ertugrul
dc.contributor.authorToppare, Levent
dc.contributor.authorYuruk, Huseyin
dc.date.accessioned2019-08-01T13:38:39Z
dc.date.available2019-08-01T13:38:39Z
dc.date.issued2010
dc.departmentNiğde ÖHÜ
dc.description.abstractA new polythiophene derivative was synthesized by electrochemical oxidative polymerization of 2,5-di( thiophen-2-yl)-1-(4-(thiophen-3-yl) phenyl)-1H-pyrrole (TTPP). The structure of the monomer was evaluated by H-1-NMR and FT-IR. The polymer (P(TTPP)) and its co-polymer with 3,4-ethylenedioxythiophene (P(TTPP-co-EDOT)) were synthesized via potentiostatic electrochemical polymerization. The resulting polymers were characterized by cyclic voltammetry (CV), FT-IR, SEM and UV-Vis spectroscopy, and conductivity measurements. Also, the spectroelectrochemical and electrochromic properties of P(TTPP-co- EDOT) were investigated. While P(TTPP) reveals no electrochromic activity, its co-polymer with EDOT has two different colours (yellow and blue). Optical contrast, switching time, lambda(max) and band gap (E-g) of (P(TTPP-co-EDOT)) were determined. (C) Koninklijke Brill NV, Leiden, 2010
dc.description.sponsorshipResearch Foundation of Nigde University (Nigde-Turkey) [FEB 2007-11]
dc.description.sponsorshipThis work was partially supported by the Research Foundation of Nigde University (FEB 2007-11) (Nigde-Turkey).
dc.identifier.doi10.1163/138577210X12634696333677
dc.identifier.endpage275
dc.identifier.issn1385-772X
dc.identifier.issn1568-5551
dc.identifier.issue3
dc.identifier.scopus2-s2.0-77953727298
dc.identifier.scopusqualityQ2
dc.identifier.startpage261
dc.identifier.urihttps://dx.doi.org/10.1163/138577210X12634696333677
dc.identifier.urihttps://hdl.handle.net/11480/4933
dc.identifier.volume13
dc.identifier.wosWOS:000282736100006
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthor[0-Belirlenecek]
dc.language.isoen
dc.publisherTAYLOR & FRANCIS LTD
dc.relation.ispartofDESIGNED MONOMERS AND POLYMERS
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectThiophene
dc.subjectelectrochemical polymerization
dc.subjectEDOT
dc.subjectco-polymer
dc.titleSynthesis, Characterization and Optoelectrochemical Properties of Poly(2,5-di(thiophen-2-yl)-1-(4-(thiophen-3-yl)phenyl)-1H-pyrrole-co-EDOT)
dc.typeArticle

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