Aminophosphines Derived from N-Phenylpiperazine and N-Ethylpiperazine: Synthesis, Oxidation Reactions, and Molybdenum Complexes

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dc.contributor.authorSarioz, Ozlem
dc.contributor.authorOznergiz, Sena
dc.contributor.authorSaracoglu, Hanife
dc.contributor.authorBuyukgungor, Orhan
dc.date.accessioned2019-08-01T13:38:39Z
dc.date.available2019-08-01T13:38:39Z
dc.date.issued2011
dc.departmentNiğde ÖHÜ
dc.description.abstractFunctionalized aminophosphine of the type Ph2PNR2 (1,2) have been synthesized by treating Ph2PCl with N-phenylpiperazine or N-ethylpiperazine. Oxidation of these ligands with aqueous hydrogen peroxide, elemental sulfur or selenium afforded the corresponding phosphine oxides 3,4, sulfides 5,6, and selenides 7,8 in good yields. The molybdenum complexes of the aminophosphines have been obtained. All new compounds were fully characterized by IR, NMR, and microanalysis, and the molecular structures of two representative compounds were determined by single-crystal X-ray crystallography. (C) 2011 Wiley Periodicals, Inc. Heteroatom Chem 22: 679-686, 2011; View this article online at wileyonlinelibrary.com. DOI 10.1002/hc.20733
dc.description.sponsorshipTUBITAK [110T572]; Nigde University [FEB 2008/20]
dc.description.sponsorshipPartial support of this work by TUBITAK (project number 110T572) and Nigde University (project number FEB 2008/20) is gratefully acknowledged.
dc.identifier.doi10.1002/hc.20733
dc.identifier.endpage686
dc.identifier.issn1042-7163
dc.identifier.issue6
dc.identifier.scopus2-s2.0-80755140076
dc.identifier.scopusqualityQ4
dc.identifier.startpage679
dc.identifier.urihttps://dx.doi.org/10.1002/hc.20733
dc.identifier.urihttps://hdl.handle.net/11480/4775
dc.identifier.volume22
dc.identifier.wosWOS:000297218100001
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthor[0-Belirlenecek]
dc.language.isoen
dc.publisherWILEY-BLACKWELL
dc.relation.ispartofHETEROATOM CHEMISTRY
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.titleAminophosphines Derived from N-Phenylpiperazine and N-Ethylpiperazine: Synthesis, Oxidation Reactions, and Molybdenum Complexes
dc.typeArticle

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