Synthesis and characterization of thermally stable oligomermetal complexes of copper(II), nickel(II), zinc(II) and cobalt(II) derived from oligo-p-nitrophenylazomethinephenol
dc.contributor.author | Vural U.S. | |
dc.contributor.author | Mart H. | |
dc.contributor.author | Demir H.O. | |
dc.contributor.author | Sariöz O. | |
dc.contributor.author | Muradoglu V. | |
dc.contributor.author | Koç M.C. | |
dc.date.accessioned | 2019-08-01T13:38:39Z | |
dc.date.available | 2019-08-01T13:38:39Z | |
dc.date.issued | 2006 | |
dc.department | Niğde ÖHÜ | |
dc.description.abstract | Thermally stable metal complexes based on oligomers were prepared by the reaction between oligo-p-nitrophenilazomethinephenol (ONPAP) and Cu(II), Ni(II), Zn(II) and Co(II) ions. The properties of oligomer-metal complexes were studied by elemental, FT-IR and magnetic moments analyses. The thermal stabilities of the oligomer-metal complexes were compared by thermogravimetric (TG) and differential thermal (DTA) analyses. According to TG, oligomer-metal complexes were stable against to temperature and thermooxidative decomposition. The weight losses of oligomer-metal complexes were found to be 5 and 50% at 200 and > 850 (Cu(II)), 172 and 600 (Ni(II)), 252 and > 850 (Zn(II)) and 174 and 510 (Co(II)), °C, respectively. Based on half degradation temperature parameters Cu(II) and Zn(II) complexes were more resistant than the others. © 2006 Chemical Society of Ethiopia. | |
dc.identifier.endpage | 226 | |
dc.identifier.issn | 1011-3924 | |
dc.identifier.issue | 2 | |
dc.identifier.scopus | 2-s2.0-33845479280 | |
dc.identifier.scopusquality | Q3 | |
dc.identifier.startpage | 219 | |
dc.identifier.uri | https://hdl.handle.net/11480/1245 | |
dc.identifier.volume | 20 | |
dc.indekslendigikaynak | Scopus | |
dc.institutionauthor | [0-Belirlenecek] | |
dc.language.iso | en | |
dc.relation.ispartof | Bulletin of the Chemical Society of Ethiopia | |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | |
dc.rights | info:eu-repo/semantics/closedAccess | |
dc.subject | Co(II) complex | |
dc.subject | Cu(II) complex | |
dc.subject | Ni(II) complex | |
dc.subject | Oligo-p-nitrophenilazomethinephenol | |
dc.subject | Oligomer metal complexes | |
dc.subject | Zn(II) complex | |
dc.title | Synthesis and characterization of thermally stable oligomermetal complexes of copper(II), nickel(II), zinc(II) and cobalt(II) derived from oligo-p-nitrophenylazomethinephenol | |
dc.type | Article |