Luminescent, Structural, and Thermal Properties of the Unusual "Anatolian" Diaspore (Zultanite) from Turkey

Basit Öğe Kaydı
dc.authorid0000-0003-0864-6861
dc.authorid0000-0003-1848-3138
dc.authorid0000-0002-9615-9045
dc.contributor.authorCanimoglu, A.
dc.contributor.authorGarcia-Guinea, J.
dc.contributor.authorCorrecher, V.
dc.contributor.authorKarabulut, Y.
dc.contributor.authorTuncer, Y.
dc.contributor.authorCan, N.
dc.date.accessioned2019-08-01T13:38:39Z
dc.date.available2019-08-01T13:38:39Z
dc.date.issued2014
dc.departmentNiğde ÖHÜ
dc.description.abstractResults are presented for the cathodoluminescence (CL) probe of an environmental scanning electron microscopy (ESEM) with an energy-dispersive spectrometry analyzer (EDS), thermoluminescence (TL), thermo X-ray diffraction in situ (TXRD), and simultaneous differential thermal analysis and thermogravimetric analysis (DTA/TGA) techniques of gem-quality zultanite samples collected from the Mugla region of southwest Turkey. Micro-Raman measurements were also performed on different zultanite orientations and preheated aliquots to study the spectral phase transition diaspore-corundum also detected by the other thermal techniques in the 450 degrees C-500 degrees C thermal range. The thermal phenomena of TL are synchronous with this dehydroxylation process, involving consecutive breaking-linking bonds of Al-O, Cr-O, Fe-O, Al-OH, Cr-OH, and Fe-OH, including the formation of hydrolyzed ions such , and and redox reactions. Assuming that zultanite oxygen atoms are distributed as a hexagonal close packed layer, the experimental spectrum CL of zultanite is characteristic of the E-2 ->(4)A(2) transitions of substitutional Cr3+ luminescent centers in positions of Al3+ in sixfold coordination.
dc.description.sponsorshipSpanish Plan Nacional de I+D+i [CGL2010-17108, FIS2011-13214-E]
dc.description.sponsorshipThe authors are grateful to projects CGL2010-17108 and FIS2011-13214-E of the Spanish Plan Nacional de I+D+i for financial support.
dc.identifier.doi10.1080/00387010.2013.800887
dc.identifier.endpage300
dc.identifier.issn0038-7010
dc.identifier.issn1532-2289
dc.identifier.issue4
dc.identifier.scopus2-s2.0-84893905737
dc.identifier.scopusqualityQ3
dc.identifier.startpage292
dc.identifier.urihttps://dx.doi.org/10.1080/00387010.2013.800887
dc.identifier.urihttps://hdl.handle.net/11480/4175
dc.identifier.volume47
dc.identifier.wosWOS:000333991800005
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthor[0-Belirlenecek]
dc.language.isoen
dc.publisherTAYLOR & FRANCIS INC
dc.relation.ispartofSPECTROSCOPY LETTERS
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectdiaspore
dc.subjectDTA
dc.subjectTurkey
dc.subjectthermoluminescence
dc.subjectXRD
dc.subjectcathodoluminescence
dc.subjectzultanite
dc.subjectTGA
dc.subjectRaman
dc.titleLuminescent, Structural, and Thermal Properties of the Unusual "Anatolian" Diaspore (Zultanite) from Turkey
dc.typeArticle

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu