Study on the Biocompatible Solvent Systems for the Reactive Extraction of Itaconic Acid

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dc.authoridKumar, Sushil/0000-0001-7114-4579
dc.authoridDatta, Dipaloy/0000-0002-2048-9064
dc.contributor.authorDatta, Dipaloy
dc.contributor.authorChomal, Neha
dc.contributor.authorUslu, Hasan
dc.contributor.authorKumar, Sushil
dc.date.accessioned2024-11-07T13:34:31Z
dc.date.available2024-11-07T13:34:31Z
dc.date.issued2019
dc.departmentNiğde Ömer Halisdemir Üniversitesi
dc.description.abstractThe separation of itaconic acid (0.2 mmol-kg(-1)) from its aqueous solution is performed by dissolving tri-n-octylamine (TOA) in the biocompatible mixtures of 1-decanol + n-dodecane, dodecanol + n-dodecane, and oleyl alcohol + n-dodecane at different compositions. Also, the physical extraction data are presented with dodecane, oleyl alcohol, dodecanol, and 1-decanol. Here, fixing the TOA composition at 20 vol %, the vol % of modifiers (oleyl alcohol, dodecanol, and 1-decanol) is changed from 20 to 60 vol % in dodecane (diluent) to find the best combination for the extraction of the acid. The extraction system comprised of 20 vol % TOA + 40 vol % dodecanol + 20 vol % n-dodecane gives the best separation efficiency (95.06%). Then, with this solvent system, equilibrium studies are carried out at different acid concentrations (0.05 and 0.251 mmol.kg(-1)). Based on the theoretical study, the insights of the extraction mechanism are determined in terms of equilibrium constants (overall and individual, K-E, K-11, and K-21) and stoichiometry (m and n) at 298 K.
dc.identifier.doi10.1021/acs.jced.9b00342
dc.identifier.endpage4285
dc.identifier.issn0021-9568
dc.identifier.issn1520-5134
dc.identifier.issue10
dc.identifier.scopus2-s2.0-85073676022
dc.identifier.scopusqualityQ2
dc.identifier.startpage4280
dc.identifier.urihttps://doi.org/10.1021/acs.jced.9b00342
dc.identifier.urihttps://hdl.handle.net/11480/16034
dc.identifier.volume64
dc.identifier.wosWOS:000490352800012
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherAmer Chemical Soc
dc.relation.ispartofJournal of Chemical and Engineering Data
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241106
dc.subject2-Methylidenebutanedioic Acid
dc.subjectOrganic-Solvent
dc.subjectAliquat 336
dc.subjectTrioctylamine
dc.subjectEquilibrium
dc.subjectToxicity
dc.subjectStrategies
dc.subjectToa
dc.titleStudy on the Biocompatible Solvent Systems for the Reactive Extraction of Itaconic Acid
dc.typeArticle

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