Synthesis and Characterization of Conducting Copolymers of Bisphenol A-Diglycidyl Ether with Thiophene Side-Groups and Pyrrole

Küçük Resim Yok

Tarih

2009

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

TAYLOR & FRANCIS INC

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

Copolymers of bisphenol A-diglycidyl ether with thiophene side-groups and pyrrole were synthesized by electrochemical polymerization. Bisphenol A-diglycidyl ether with thiophene side-groups (DGEBATh) was obtained from the reaction between bisphenol A-diglycidyl ether (DGEBA) and thiophene-3-acetic acid. The syntheses of copolymers of DGEBATh and pyrrole were achieved electrochemically using three different supporting electrolytes, p-toluene sulfonic acid (PTSA), sodium dodecyl sulfate (SDS) and tetrabutylammonium tetrafluoroborate (TBAFB). Characterizations of DGEBATh and copolymers were performed by combination of techniques including cyclic voltammetry, scanning electron microscopy, gel permeation chromatography, differential scanning calorimetry, 1H-NMR and FT-IR. The conductivities were measured by the four-probe technique.

Açıklama

Anahtar Kelimeler

Conducting copolymers, bisphenol A, thiophene, pyrrole, electrochemical polymerization

Kaynak

JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY

WoS Q Değeri

Q3

Scopus Q Değeri

Q2

Cilt

46

Sayı

6

Künye