An Application of a Schiff-Base Type Reaction in the Synthesis of a New Rhodamine-Based Hg(II)-Sensing Agent
Küçük Resim Yok
Tarih
2019
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Springer/Plenum Publishers
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
A facile synthesis procedure, whereby 9-Anthraldehyde (AA) is coupled to aminated rhodamine (AR) via a Schiff base-type reaction, is reported. The applicability and performance of the obtained material (AA-AR) as a sensing agent was studied towards 16 metal cations (i.e. Li+, Na+, Ag+, Ca2+, Ba2+, Co2+, Cs+, Cu2+, Mg2+, Hg2+, Mn2+, Pb2+, Ni2+, Sr2+, Zn2+, Al3+). Among the studied metals, an extraordinary selectivity was observed for Hg2+, and the observed selectivity was found not to be influenced by the presence of other cations and some common anions (i.e. Br-, Cl-, I-, HPO42-, H2PO4-, NO3-, NO2-, ClO4-, AcO-, HSO4-, SO42-, Cr2O7-, CO32-, OH- and HCO3-). The material, AA-AR, exhibited such a high selectivity and sensitivity towards Hg2+ that it could be detected even by naked eyes. The Hg2+-sensing property of AA-AR was found not to be limited to colorimetric detections so that a high fluorescent nature of the compound was also observed upon binding Hg2+ ion. The detection limit, which is correspondent to fluorescence emission intensity, was found as 0.87 mu M. The underlying mechanism of sensing property was studied by using some spectroscopic techniques such as FT-IR, H-1-NMR, C-13-NMR, and UV-Vis. (Job-plot). In the final course of the experiments, the performance of AA-AR in cell-imaging was also studied, and even trace amounts of Hg2+ in living cells could be detected by the studied probe. Thus, the applicability of a new synthesis approach in producing a highly efficient new fluorescence sensor for the detection of Hg2+ ions is discussed in detail.
Açıklama
Anahtar Kelimeler
Anthracene, Cell imaging, Fluorescence sensor, Mercury, Rhodamine, Schiff base
Kaynak
Journal of Fluorescence
WoS Q Değeri
Q3
Scopus Q Değeri
Q1
Cilt
29
Sayı
6
