Synthesis of reduced graphene oxide-fungal hyphae biochar/iron oxide composite: characterization, adsorption performance, and removal mechanisms

Basit Öğe Kaydı
dc.authoridZAN, RECEP/0000-0001-6739-4348
dc.authoridAkarsu, Ceyhun/0000-0002-0168-9941
dc.authoridMADENLI, Ozgecan/0000-0002-8673-3963
dc.contributor.authorDeveci, E. U.
dc.contributor.authorMadenli, O.
dc.contributor.authorAkarsu, C.
dc.contributor.authorZan, R.
dc.date.accessioned2024-11-07T13:32:39Z
dc.date.available2024-11-07T13:32:39Z
dc.date.issued2024
dc.departmentNiğde Ömer Halisdemir Üniversitesi
dc.description.abstractIn this study, a novel biochar, iron-impregnated reduced graphene oxide-fungal hyphae, named AOBC-rGO, was synthesized as an innovative approach for the removal of Cr(VI) ions from water. A scanning electron microscope showed the formation of large agglomerates on the surface of biochar samples while Raman analysis showed D and G bands at 1350 and 1580 cm(-1) respectively as the proof of polyaromatic hydrocarbons and graphitic material. The surface area of the AOBC-rGO was determined as 58.5650 m(2) g(-1). To evaluate the efficacy of AOBC-rGO, the effect of initial chromium concentration (25, 50, 100, 150 and 200 mg L-1), pH (2, 5, 7, 9 and 11), retention time (0, 5, 10, 20, 30, 40, 50, 60 and 90 min), and adsorbent dose (100, 300 and 500 mg L-1) was investigated in batch experiments for synthetic and real wastewater samples. Adsorption tests showed that the biochar adsorption capacity was 1116.01 mg g(-1). Furthermore, findings suggest that the chromium sorption on AOBC-rGO fits with the pseudo-second-order model and Freundlich isotherm model (R-2 > 0.93), indicating a heterogeneous surface with a dominant chemisorption mechanism. Thus, AOBC-rGO can be used as an effective adsorbent to remove heavy metals from wastewater.
dc.description.sponsorshipTrkiye Bilimsel ve Teknolojik Arascedil;timath;rma Kurumu [CAYDAG-120Y087]; Scientific and Technological Research Council of Turkey (TUBITAK) [TR62/18/URET/0036]; Cukurova Development Agency (CKA)
dc.description.sponsorshipThis research was funded by The Scientific and Technological Research Council of Turkey (TUBITAK) (CAYDAG-120Y087) and Cukurova Development Agency (CKA) (TR62/18/URET/0036).
dc.identifier.doi10.1007/s13762-024-05817-z
dc.identifier.issn1735-1472
dc.identifier.issn1735-2630
dc.identifier.scopus2-s2.0-85196009313
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1007/s13762-024-05817-z
dc.identifier.urihttps://hdl.handle.net/11480/15539
dc.identifier.wosWOS:001248452800002
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer
dc.relation.ispartofInternational Journal of Environmental Science and Technology
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241106
dc.subjectBio-nanocomposite
dc.subjectBiochar
dc.subjectChromium(VI)
dc.subjectIsotherm
dc.subjectKinetic
dc.subjectMagnetic modification
dc.titleSynthesis of reduced graphene oxide-fungal hyphae biochar/iron oxide composite: characterization, adsorption performance, and removal mechanisms
dc.typeArticle

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu