Synthesis and complex formation of substituted amino-2-naphthylglyoximes of unsymmetrical vic-dioximes
Küçük Resim Yok
Tarih
2003
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
anti-2-Naphthylchloroglyoxime has been synthesized by chlorination of anti-2-naphthylglyoxime. Reaction with aryl-or arylalkylamines in EtOH between 15°C and 20°C gives unsymmetrical vic-dioximes, namely, anilino-2-naphthylglyoxime (L1H2), benzylamino-2-naphthylglyoxime (L2H2), p-toluidino-2-naphthylglyoxime (L3H2) 1-naphthylamino-2-naphthylglyoxime (L4H2). The Ni(II) and Cu(II) complexes of these ligands are square-planar while the Co(II) complexes are octahedral with water molecules as axial ligands. 1H NMR, IR and elemental analyses data of the complexes and ligands are discussed.
Açıklama
Anahtar Kelimeler
Kaynak
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
WoS Q Değeri
Q4
Scopus Q Değeri
N/A
Cilt
33
Sayı
5
