Tb-doped MgAl2O4 phosphors: A study of structural and luminescence characteristics

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dc.authoridMADKHALI, Osama/0000-0001-9397-9956
dc.contributor.authorHalefoglu, Y. Z.
dc.contributor.authorSouadi, G.
dc.contributor.authorAyvacikli, M.
dc.contributor.authorBulcar, K.
dc.contributor.authorTopaksu, M.
dc.contributor.authorCanimoglu, A.
dc.contributor.authorMadkhali, O.
dc.date.accessioned2024-11-07T13:35:01Z
dc.date.available2024-11-07T13:35:01Z
dc.date.issued2024
dc.departmentNiğde Ömer Halisdemir Üniversitesi
dc.description.abstractIn the MgO-Al2O3 system, magnesium aluminate spinel (MgAl2O4) is a technologically significant compound due to its unique properties, including a high melting point, low thermal conductivity, excellent thermal shock resistance, chemical inertness, and robust mechanical strength. This compound has diverse applications in re-fractory materials, catalyst supports, moisture sensors, nuclear techniques, insulating materials, and even mili-tary applications. While rare-earth elements are commonly used as dopants in luminescent materials, limited research exists on doping of Tb3+ ions in magnesium aluminate. This study investigates the luminescence properties of Tb3+ doped synthesis magnesium aluminate materials, shedding light on this underexplored area. The combustion method is employed for synthesis, known for producing nano-sized powders with exceptional luminescent properties. Additionally, this study explores Sm3+ ion doping in magnesium aluminate materials and their luminescence properties. Using the combustion synthesis method, structural attributes of Tb3+-doped MgAl2O4 nanophosphors are meticulously examined. Through X-ray diffraction (XRD) and Fourier-transform infrared (FTIR) analyses, coupled with excitation and emission spectra, a comprehensive investigation of the luminescent provide behavior at room temperature is provided. The XRD data reveal Tb3+ doped MgAl2O4 phosphors exhibit a single phase with face centred cubic structure belonging to the Fd3 m space group, consistent with the standard JCPDS files (No. 21-1152). Excitation and emission spectra offer valuable insights into the energy transitions within the Tb3+-doped MgAl2O4 phosphors. Furthermore, the study explores the effects of varying Tb3+ ion concentrations on the luminescent properties, revealing an optimal doping concentration of 5 wt% Tb for maximizing emission intensity. Concentration quenching, primarily attributed to dipole-dipole (d-q) interactions, is observed at higher Sm3+ concentrations. In conclusion, this research enhances our understanding of rare-earth ion doping in luminescent materials and highlights the potential applications of Tb3+-doped MgAl2O4 nanophosphors, which offer promise for various technological applications, including lighting and displays.
dc.description.sponsorshipDeputyship for Research & Innovation, Ministry of Education in Saudi Arabia [ISP23-139]
dc.description.sponsorshipThe authors extend their appreciation to the Deputyship for Research & Innovation, Ministry of Education in Saudi Arabia for funding this research work through the project number ISP23-139.
dc.identifier.doi10.1016/j.apradiso.2023.111101
dc.identifier.issn0969-8043
dc.identifier.issn1872-9800
dc.identifier.pmid37925901
dc.identifier.scopus2-s2.0-85175568557
dc.identifier.scopusqualityQ3
dc.identifier.urihttps://doi.org/10.1016/j.apradiso.2023.111101
dc.identifier.urihttps://hdl.handle.net/11480/16288
dc.identifier.volume203
dc.identifier.wosWOS:001107691700001
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherPergamon-Elsevier Science Ltd
dc.relation.ispartofApplied Radiation and Isotopes
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241106
dc.subjectXRD
dc.subjectPhotoluminescence
dc.subjectDipole -dipole interaction
dc.titleTb-doped MgAl2O4 phosphors: A study of structural and luminescence characteristics
dc.typeArticle

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