Synthesis and characterization of a new soluble conducting polymer and its electrochromic devices

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dc.authorid0000-0002-7324-0385
dc.contributor.authorSahin, Elif
dc.contributor.authorSahmetlioglu, Ertugrul
dc.contributor.authorAkhmedov, Idris M.
dc.contributor.authorTanyeli, Cihangir
dc.contributor.authorToppare, Levent
dc.date.accessioned2019-08-01T13:38:39Z
dc.date.available2019-08-01T13:38:39Z
dc.date.issued2006
dc.departmentNiğde ÖHÜ
dc.description.abstractA new polythiophene derivative was synthesized by both chemical and electrochemical oxidative polymerization of 1-(perfluorophenyl)-2,5-di(2-thienyl)-1H-pyrrole (FPTPy). The structures of both the monomer and the soluble polymer were elucidated by nuclear magnetic resonance (H-1-NMR) and fourier transform infrared (FTIR). Polymer of FPTPy was also synthesized via potentiostatic electrochemical polymerization in acetonitrile (AN)/NaClO4/LiClO4 (0.1 M:0.1 M) Solvent-electrolyte couple. Characterizations of the resulting insoluble polymer were performed by cyclic voltammetry (CV), FTIR, scanning electron microscopy (SEM) and UV-Vis Spectroscopy. Four-probe technique was used to measure the conductivities of the samples. Moreover, the spectroelectrochemical and electrochromic properties of the polymer film were investigated. In addition, dual type polymer electrochromic devices (ECDs) based on P(FPTPy) with poly(3,4-ethylenedioxythiophene) (PEDOT) were constructed. Spectroelectrochemistry, electrochromic switching and open circuit stability of the devices were studied. They were found to have good switching times, reasonable contrasts and optical memories. (C) 2006 Elsevier B.V. All rights reserved.
dc.identifier.doi10.1016/j.orgel.2006.04.001
dc.identifier.endpage362
dc.identifier.issn1566-1199
dc.identifier.issue5
dc.identifier.scopus2-s2.0-33748801474
dc.identifier.scopusqualityQ1
dc.identifier.startpage351
dc.identifier.urihttps://dx.doi.org/10.1016/j.orgel.2006.04.001
dc.identifier.urihttps://hdl.handle.net/11480/5483
dc.identifier.volume7
dc.identifier.wosWOS:000241956800015
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthor[0-Belirlenecek]
dc.language.isoen
dc.publisherELSEVIER SCIENCE BV
dc.relation.ispartofORGANIC ELECTRONICS
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectconducting polymers
dc.subjectUV-vis spectroscopy
dc.subjectelectrochemistry
dc.subjectmorphology
dc.titleSynthesis and characterization of a new soluble conducting polymer and its electrochromic devices
dc.typeArticle

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