Synthesis and characterization of poly{2-[3-(1H-pyrrol-2-yl)phenyl]-1H-pyrrole} and its copolymer with EDOT

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dc.authorid0000-0002-
dc.authorid0000-0002-7324-0385
dc.contributor.authorTurac, Ersen
dc.contributor.authorAk, Metin
dc.contributor.authorSahmetlioglu, Ertugrul
dc.contributor.authorSener, M. Kasim
dc.contributor.authorKaya, Mehmet Arif
dc.date.accessioned2019-08-01T13:38:39Z
dc.date.available2019-08-01T13:38:39Z
dc.date.issued2011
dc.departmentNiğde ÖHÜ
dc.description.abstractA pyrrole-functionalized monomer 2-[3-(1H-pyrrol-2-yl)phenyl]-1H-pyrrole (PyPhPy) was synthesized. The structure of monomer was investigated by Nuclear Magnetic Resonance (H-1 NMR) and Fourier Transform Infrared (FTIR) spectroscopy. The chemical polymerization of PyPhPy (CPyPhPy) was realized using FeCl3 as the oxidant. The electrochemical oxidative polymerization of polymer P(PyPhPy) and its copolymer with 3,4-ethylenedioxythiophene poly(2-[3-(1H-pyrrol-2-yl)phenyl]-1H-pyrrole-co-3,4-ethylenedioxythiophene) [P(PyPhPy-co-EDOT)] were achieved via potentiodynamic method by using NaClO4/LiClO4 as the supporting electrolyte in CH3CN. Characterizations of the resulting polymers were performed by cyclic voltammetry (CV), FTIR, scanning electron microscopy (SEM), UV-Visible spectrophotometry (UV-Vis) and thermogravimetry analyses (TGA). Electrical conductivity of CPyPhPy, P(PyPhPy), and P(PyPhPyco-EDOT) were measured by four-probe technique.
dc.identifier.doi10.1134/S1070363211120164
dc.identifier.endpage2516
dc.identifier.issn1070-3632
dc.identifier.issue12
dc.identifier.scopus2-s2.0-84856951055
dc.identifier.scopusqualityQ4
dc.identifier.startpage2510
dc.identifier.urihttps://dx.doi.org/10.1134/S1070363211120164
dc.identifier.urihttps://hdl.handle.net/11480/4665
dc.identifier.volume81
dc.identifier.wosWOS:000299519300016
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthor[0-Belirlenecek]
dc.language.isoen
dc.publisherMAIK NAUKA/INTERPERIODICA/SPRINGER
dc.relation.ispartofRUSSIAN JOURNAL OF GENERAL CHEMISTRY
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.titleSynthesis and characterization of poly{2-[3-(1H-pyrrol-2-yl)phenyl]-1H-pyrrole} and its copolymer with EDOT
dc.typeArticle

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