Synthesis and characterization of triethylammonium 2-(diphenylphosphinoamino)-5-methylbenzenesulfonate and use of it as a new complexing agent in solvent extraction of Ni (II) ions from water

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dc.contributor.authorSarioz, Ozlem
dc.contributor.authorSurme, Yavuz
dc.contributor.authorMuradoglu, Vefa
dc.contributor.authorMalgac, Burcu
dc.date.accessioned2019-08-01T13:38:39Z
dc.date.available2019-08-01T13:38:39Z
dc.date.issued2013
dc.departmentNiğde ÖHÜ
dc.description.abstractTriethylammonium 2-(diphenylphosphinoamino)-5-methylbenzenesulfonate (2) has been synthesized by treating Ph2PCl with 4-aminotoluene-3-sulfonic acid. The new compound was characterized by IR, H-1- and P-31-NMR, and elemental analysis. Liquid-liquid extraction of Ni (II) ions using synthesized aminophosphine derivative as new extractants was studied. The influence of critical parameters on the extraction properties of aminophosphine derivative such as solution pH and ligand mass were investigated. The liquid-liquid extraction ability of newly synthesized compound has also been compared another aminophosphine derivative (1). UV-vis spectrophotometry used to determine the liquid/liquid extraction efficiencies of Ni (II) metal ions at various conditions. Both of the extractant was found to be efficient for extraction of Ni (II) metal ions with recoveries of 84.8 and 81.5% for ligands 1 and 2 respectively.
dc.description.sponsorshipProject Development and Support Unit of The University of Nigde [FEB 2012/07]
dc.description.sponsorshipWe are grateful to Project Development and Support Unit of The University of Nigde (Project No: FEB 2012/07) for financial support.
dc.identifier.doi10.1080/19443994.2012.759159
dc.identifier.endpage5413
dc.identifier.issn1944-3994
dc.identifier.issue28-30
dc.identifier.scopus2-s2.0-84882723610
dc.identifier.scopusqualityQ3
dc.identifier.startpage5409
dc.identifier.urihttps://dx.doi.org/10.1080/19443994.2012.759159
dc.identifier.urihttps://hdl.handle.net/11480/4369
dc.identifier.volume51
dc.identifier.wosWOS:000323194300003
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthor[0-Belirlenecek]
dc.language.isoen
dc.publisherTAYLOR & FRANCIS INC
dc.relation.ispartofDESALINATION AND WATER TREATMENT
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectAminophosphines
dc.subjectOrganophosphorus compounds
dc.subjectLiquid-liquid extraction
dc.subjectSeparation
dc.subjectSelectivity
dc.subjectNickel
dc.titleSynthesis and characterization of triethylammonium 2-(diphenylphosphinoamino)-5-methylbenzenesulfonate and use of it as a new complexing agent in solvent extraction of Ni (II) ions from water
dc.typeArticle

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