The Synthesis and Investigation of Liquid-Liquid Extraction Capability of N-Diphenylphosphino-N-ethylaniline and Its Chalcogenide Derivatives

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dc.contributor.authorAkkuslu, Y.
dc.contributor.authorSarioz, O.
dc.date.accessioned2024-11-07T13:24:13Z
dc.date.available2024-11-07T13:24:13Z
dc.date.issued2019
dc.departmentNiğde Ömer Halisdemir Üniversitesi
dc.description.abstractThe aminophosphine ligand was synthesized by the reaction of N-ethylaniline with chlorodiphenylphosphine in the presence of triethylamine at low temperature. Oxidation of the ligand with elemental sulfur or selenium afforded the corresponding aminophosphine sulfide and selenide. The compounds were characterized by elemental analyses, IR, H-1 and P-31 NMR. N-diphenylphosphino-N-ethylaniline and its chalcogen derivatives were used as ligands in solvent extraction of metal picrates such as Cd2+ and Ni2+ from the aqueous to the organic phase. Influences of parameters such as pH of the aqueous phase, solvent, extraction time, and extradant concentration were investigated to determine the extraction ability of ligands for metal ions. Results of the experiments showed that an extractability of 95.5 and 97.8%, respectively for Ni2+, and Cd2+ at pH 2 could be achieved.
dc.description.sponsorshipResearch Projects Unit of Nigde Omer Halisdemir University [FEB 2015/34]
dc.description.sponsorshipThis study was supported financially by the Research Projects Unit of Nigde Omer Halisdemir University with project no. FEB 2015/34.
dc.identifier.doi10.1134/S1070427219060119
dc.identifier.endpage822
dc.identifier.issn1070-4272
dc.identifier.issn1608-3296
dc.identifier.issue6
dc.identifier.scopus2-s2.0-85070335929
dc.identifier.scopusqualityQ3
dc.identifier.startpage817
dc.identifier.urihttps://doi.org/10.1134/S1070427219060119
dc.identifier.urihttps://hdl.handle.net/11480/13986
dc.identifier.volume92
dc.identifier.wosWOS:000479143900011
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherPleiades Publishing Inc
dc.relation.ispartofRussian Journal of Applied Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241106
dc.subjectAminophosphines
dc.subjectchalcogenides
dc.subjectheavy metals
dc.subjectsolvent extraction
dc.titleThe Synthesis and Investigation of Liquid-Liquid Extraction Capability of N-Diphenylphosphino-N-ethylaniline and Its Chalcogenide Derivatives
dc.typeArticle

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