Synthesis and Characterization of Aminophosphines, Bis(amino) phosphine Derivatives, and Their Molybdenum(0) Complexes

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dc.contributor.authorSarioz, Ozlem
dc.contributor.authorSerindag, Osman
dc.contributor.authorAbdullah, Meysun I.
dc.date.accessioned2019-08-01T13:38:39Z
dc.date.available2019-08-01T13:38:39Z
dc.date.issued2009
dc.departmentNiğde ÖHÜ
dc.description.abstractFunctionalized bis(amino)phosphines of the type PhP(NHR)(2) (1a-c) and aminophosphines of the type Ph(2)PNHR (2a-c) have been synthesized by treating PhPCl(2) or Ph(2)PCl with corresponding primary amines of H(2)N-R where R = -CH(2)SO(3)H, -C(6)H(4)SO(3)H, and benzo-15-crown-5. The molybdenum(0) complex of the aminophosphine (3) has been obtained by reacting cis-[Mo(CO)(4)(bipy)] with aminophosphine (2c). The synthesized aminophosphines, bis(amino) phosphines, and the molybdenum(0) complex have been characterized by IR, (1)H NMR, (31)P NMR, and MS spectroscopic techniques and by elemental analysis.
dc.description.sponsorshipResearch Foundation of The University of Nigde (NUAF); Chemistry Department of The University of Cukurova
dc.description.sponsorshipWe are grateful to the Research Foundation of The University of Nigde (NUAF) for financial support and the Chemistry Department of The University of Cukurova for providing research facilities.
dc.identifier.doi10.1080/10426500802341275
dc.identifier.endpage1795
dc.identifier.issn1042-6507
dc.identifier.issue7
dc.identifier.scopus2-s2.0-70449652153
dc.identifier.scopusqualityQ4
dc.identifier.startpage1785
dc.identifier.urihttps://dx.doi.org/10.1080/10426500802341275
dc.identifier.urihttps://hdl.handle.net/11480/5152
dc.identifier.volume184
dc.identifier.wosWOS:000277672400014
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthor[0-Belirlenecek]
dc.language.isoen
dc.publisherTAYLOR & FRANCIS LTD
dc.relation.ispartofPHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectAminophosphine
dc.subjectbis(amino)phosphines
dc.subjectcrown ethers
dc.subjectmolybdenum(0) complexes
dc.titleSynthesis and Characterization of Aminophosphines, Bis(amino) phosphine Derivatives, and Their Molybdenum(0) Complexes
dc.typeArticle

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