Adsorption of nitroaniline positional isomers on humic acid-incorporated monolithic cryogel discs: Application of ligand-exchange concept
Küçük Resim Yok
Tarih
2017
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Elsevier Sci Ltd
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Adsorptive removal of some nitroaniline positional isomers was studied by using a humic acid-cryogel based monolithic adsorbent (MLHA). Monolithic material was characterized by FTIR and SEM techniques. The adsorbent was turned into a ligand exchanger form (i.e. Cu-MLHA) by Cu(II) loading. The amount of Cu( II) bound to the monolithic discs was determined by AAS analyses. The effect of contact time and initial nitroaniline concentration on adsorption was studied, and the fit of some isotherm models was analyzed. Maximum observable adsorption capacities recorded on Cu- MLHA were found to be around 150-180mg/g, and the capacities decreased in the order 3-nitroaniline > 4-nitroaniline > 2-nitroaniline.
Açıklama
Anahtar Kelimeler
Adsorption, Cryogel, Humic acid, Ligand-exchange, Monolithic adsorbent, Nitroaniline
Kaynak
Journal of Environmental Chemical Engineering
WoS Q Değeri
N/A
Scopus Q Değeri
Q1
Cilt
5
Sayı
3