Measurement and Correlational Study of Phase Equilibria in Aqueous Solutions of N,N-Dimethylacetamide with 1-Pentanol and 1-Hexanol at 298.15 and 308.15 K

Basit Öğe Kaydı
dc.authoridMERZOUGUI, Abdelkrim/0000-0003-0587-8974
dc.contributor.authorLami, Nassima
dc.contributor.authorMerzougui, Abdelkrim
dc.contributor.authorUslu, Hasan
dc.date.accessioned2024-11-07T13:32:16Z
dc.date.available2024-11-07T13:32:16Z
dc.date.issued2020
dc.departmentNiğde Ömer Halisdemir Üniversitesi
dc.description.abstractTie-line data were determined for the systems (water + N,N-dimethylacetamide + 1-pentanol) and (water + N,Ndimethylacetamide + 1-hexanol) at the temperatures of 298.15 and 308.15 K under 101.1 KPa. The phase diagrams for these systems are of type I according to the Treyball classification. The thermodynamic consistency of the measured tie-line data was verified using the Hand and Othmer-Tobias equations. The distribution ratios (D) and selectivity (S) values were computed according to the measured tie-line data to assess the extracting behaviors of the selected solvents. The experimental data were correlated using the nonrandom two liquid and the universal quasichemical activity coefficient equations and the Elephant Herding Optimization Algorithm (EHA). EHA is an emerging nature-inspired stochastic global optimization method, and it has been used for liquid-liquid equilibrium (LLE) parameter estimation of local composition models in multicomponent mixtures. The performance of this new swarm-based metaheuristic search method for LLE modeling with and without the closure equation has been analyzed.
dc.identifier.doi10.1021/acs.jced.9b01029
dc.identifier.endpage2956
dc.identifier.issn0021-9568
dc.identifier.issn1520-5134
dc.identifier.issue6
dc.identifier.scopus2-s2.0-85085759760
dc.identifier.scopusqualityQ2
dc.identifier.startpage2947
dc.identifier.urihttps://doi.org/10.1021/acs.jced.9b01029
dc.identifier.urihttps://hdl.handle.net/11480/15330
dc.identifier.volume65
dc.identifier.wosWOS:000541740100003
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherAmer Chemical Soc
dc.relation.ispartofJournal of Chemical and Engineering Data
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_20241106
dc.subjectLiquid-Liquid Equilibrium
dc.subjectPlus Water
dc.subjectTernary-Systems
dc.subjectDichloromethane
dc.subjectExtraction
dc.subjectAlgorithm
dc.subjectParameter
dc.titleMeasurement and Correlational Study of Phase Equilibria in Aqueous Solutions of N,N-Dimethylacetamide with 1-Pentanol and 1-Hexanol at 298.15 and 308.15 K
dc.typeArticle

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu