Synthesis and characterization of new Schiff bases and their cobalt(II), nickel(II), copper(II), zinc(II), cadmium(II) and mercury(II) complexes
Küçük Resim Yok
Tarih
2005
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
TAYLOR & FRANCIS INC
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Nickel(II), copper( II), cobalt( II), zinc( II), cadmium( II) and mercury( II) complexes chelates containing the Schiff base ligands methyliminoisonitroso-2-acetylnaphthalene (HL1) and benzyliminoisonitroso-2-acetylnaphthalene (HL2) have been prepared. The results suggest that the Schiff bases function as bidentate ligands and indicate a mononuclear structure for the Cu(II) complexes with square-planar geometry. The Ni(II), Zn(II), Hg(II) and Cd(II) complexes are of tetrahedral geometry and the Co(II) complexes with octahedral geometry with water molecules at the axial positions. These compounds have been characterized by elemental analyses, magnetic susceptibility, mass, IR, UV, H-1 and C-13 NMR spectroscopy.
Açıklama
Anahtar Kelimeler
Schiff base ligands, spectra, transition metal complexes
Kaynak
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY
WoS Q Değeri
Q4
Scopus Q Değeri
N/A
Cilt
35
Sayı
5
