SYNTHESIS, CHARACTERIZATION AND AB INITIO CALCULATIONS OF AMINOPHOSPHINE DERIVED FROM 4-BENZYLPIPERIDINE, ITS CHALCOGENIDE DERIVATIVES AND MOLYBDENUM(0) COMPLEX

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dc.authorid0000-0002-4717-8602
dc.contributor.authorSarioz, Ozlem
dc.contributor.authorCirak, Cagri
dc.contributor.authorMuradoglu, Vefa
dc.contributor.authorOznergiz, Sena
dc.date.accessioned2019-08-01T13:38:39Z
dc.date.available2019-08-01T13:38:39Z
dc.date.issued2014
dc.departmentNiğde ÖHÜ
dc.description.abstractFunctionalized monoaminophosphine PPh2NC5H9CH2C6H5 has been synthesized by treating Ph2PCl with 4-benzylpiperidine. The ligand reacts with aqueous hydrogen peroxide, elemental sulfur or selenium to give the corresponding chalcogenides in good yield. The molybdenum complex of the aminophosphine has been obtained. All of the new compounds were obtained in good yields and were characterized by IR, NMR, elemental analysis. Theoretical calculations were carried out by using the Hartree-Fock and density functional methods with the 6-31G(d) basis set. [Supplementary materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements for the following free supplemental files: Additional tables and figures.]
dc.description.sponsorshipTUBITAK [110T572]
dc.description.sponsorshipSupport of this work by TUBITAK (Project number 110T572) is gratefully acknowledged.
dc.identifier.doi10.1080/10426507.2013.819864
dc.identifier.endpage352
dc.identifier.issn1042-6507
dc.identifier.issn1563-5325
dc.identifier.issue3
dc.identifier.scopus2-s2.0-84894149260
dc.identifier.scopusqualityQ4
dc.identifier.startpage343
dc.identifier.urihttps://dx.doi.org/10.1080/10426507.2013.819864
dc.identifier.urihttps://hdl.handle.net/11480/4278
dc.identifier.volume189
dc.identifier.wosWOS:000330265700005
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthor[0-Belirlenecek]
dc.language.isoen
dc.publisherTAYLOR & FRANCIS LTD
dc.relation.ispartofPHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectPhosphines
dc.subjectaminophosphines
dc.subjectaminophosphine chalcogenides
dc.subjectchalcogenides
dc.subjectcondensation reaction
dc.subjectaminophosphine complexes
dc.titleSYNTHESIS, CHARACTERIZATION AND AB INITIO CALCULATIONS OF AMINOPHOSPHINE DERIVED FROM 4-BENZYLPIPERIDINE, ITS CHALCOGENIDE DERIVATIVES AND MOLYBDENUM(0) COMPLEX
dc.typeArticle

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