The synthesis and thermal properties of oligo-3-hydroxybenzaldehyde synthesized by oxidative polycondensation

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dc.contributor.authorMart, H
dc.contributor.authorSokmen, T
dc.contributor.authorYuruk, H
dc.date.accessioned2019-08-01T13:38:39Z
dc.date.available2019-08-01T13:38:39Z
dc.date.issued2006
dc.departmentNiğde ÖHÜ
dc.description.abstractPolymerization of 3-hydroxybenzaldehyde was investigated by oxidative polycondensation (OP) method. No polycondensation reaction was observed both in acidic (in CH3COOH) and organic (in THF) media. Polycondensation was carried out with hydrogenperoxide (H2O2) in an aqueous alkaline medium at 90 degrees C. The product was characterized by H-1 NMR, C-13 NMR, FTIR, UV-vis, and elemental analysis. The number average molecular weight, mass average molecular weight, and polydispersity index values of O-3HBA were found to be 3600, 8000 g mol(-1), and 2.22, respectively. The product (O-3HBA) with reactive aldehyde and hydroxyl group was soluble in most polar organic solvents and was composed of phenylene units. Thermal properties of the oligomer were investigated by thermogravimetric analyses under an air atmosphere. The weight loss of O-3HBA was found to be 5 and 50% at 231 and > 1000 degrees C, respectively. The carboneous residue of the O-3HBA was 54% at 1000 degrees C. (c) 2006 Wiley Periodicals, Inc.
dc.identifier.doi10.1002/app.23537
dc.identifier.endpage897
dc.identifier.issn0021-8995
dc.identifier.issue2
dc.identifier.scopus2-s2.0-33745121216
dc.identifier.scopusqualityQ2
dc.identifier.startpage892
dc.identifier.urihttps://dx.doi.org/10.1002/app.23537
dc.identifier.urihttps://hdl.handle.net/11480/5501
dc.identifier.volume101
dc.identifier.wosWOS:000237753100014
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthor[0-Belirlenecek]
dc.language.isoen
dc.publisherJOHN WILEY & SONS INC
dc.relation.ispartofJOURNAL OF APPLIED POLYMER SCIENCE
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectoxidative polycondensation
dc.subjectpolyaromatics
dc.subjectpolyphenols
dc.subjectoligomers
dc.titleThe synthesis and thermal properties of oligo-3-hydroxybenzaldehyde synthesized by oxidative polycondensation
dc.typeArticle

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