Adsorptive removal of Methylene blue and Methyl orange from aqueous media by carboxylated diaminoethane sporopollenin: On the usability of an aminocarboxilic acid functionality-bearing solid-stationary phase in column techniques

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dc.authorid0000-0001-6808-2282
dc.contributor.authorAyar, Ahmet
dc.contributor.authorGezici, Orhan
dc.contributor.authorKucukosmanoglu, Muhittin
dc.date.accessioned2019-08-01T13:38:39Z
dc.date.available2019-08-01T13:38:39Z
dc.date.issued2007
dc.departmentNiğde ÖHÜ
dc.description.abstractThe adsorption phenomena of Methylene blue (MB) and Methyl orange (MO) on a carboxylated diaminoethane sporopollenin (CDAE-S) solid phase were investigated in a column arrangement by using breakthrough technique. The adsorption phenomena were evaluated using some common adsorption isotherm models and Scatchard plot analysis, and obtained results were interpreted for evaluating the usability of CDAE-S for removal, recovery and preconcentration of the studied dyes both at the laboratory and industrial scales. On the basis of Scatchard plot analysis, the interaction types between the CDAE-S and the studied dyes were criticized in terms of affinity phenomena. Thus, the usability of a biomacromolecule-derived material, CDAE-S, as a cheap, environmentally-friendly and effective solid-stationary phase exhibiting both cation-exchange and anion-exchange characteristics at the same time, is discussed through the present study. Besides, from the obtained results, the protonated CDAE-S, which functionally resembles an amino acid structure, are presented as a two-in-one solid- stationary phase, and its adaptability to common processes performed under column conditions is also drawn in detail. (C) 2006 Elsevier B.V. All rights reserved.
dc.identifier.doi10.1016/j.jhazmat.2006.12.009
dc.identifier.endpage193
dc.identifier.issn0304-3894
dc.identifier.issue45323
dc.identifier.pmid17208364
dc.identifier.scopus2-s2.0-34250335727
dc.identifier.scopusqualityQ1
dc.identifier.startpage186
dc.identifier.urihttps://dx.doi.org/10.1016/j.jhazmat.2006.12.009
dc.identifier.urihttps://hdl.handle.net/11480/5367
dc.identifier.volume146
dc.identifier.wosWOS:000248159700024
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.institutionauthor[0-Belirlenecek]
dc.language.isoen
dc.publisherELSEVIER SCIENCE BV
dc.relation.ispartofJOURNAL OF HAZARDOUS MATERIALS
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectbreakthrough curve
dc.subjectdye
dc.subjectHPLC
dc.subjection-exchange
dc.subjectscatchard plot analysis
dc.subjectsorption
dc.subjectSPE
dc.titleAdsorptive removal of Methylene blue and Methyl orange from aqueous media by carboxylated diaminoethane sporopollenin: On the usability of an aminocarboxilic acid functionality-bearing solid-stationary phase in column techniques
dc.typeArticle

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