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    Synthesis of New Type of Macrocyclic Lactones Functionalized with Different Groups and Investigation of Their Metal Binding Abilities
    (POLISH CHEMICAL SOC, 2009) Ertul, S.; Bayrakci, M.
    New type of macrocyclic lactones functionalized with different groups were synthesized by reaction of the dihydroxy compounds such as 5a-d with suitable glycolyl chloride such as tri, tetra dicarboxylic acid dichloride derivatives. Their metal complexes with NaClO4 center dot H2O, KClO4 and Ba(ClO4)(2)center dot H2O were studied. Furthermore, their metal-picrate extraction studies with metal salts such as Na+, K+, Cu2+, Ni2+ and Hg2+ from aqueous phase to organic phase were attempted. All the structures of the ligands and complexes were confirmed by H-I-, C-13-NMR, IR, UV-Vis, MS and elemental analyses methods.
  • Küçük Resim Yok
    Öğe
    Synthesis of new type of macrocyclic lactones functionalized with different groups and investigation of their metal binding abilities
    (2009) Ertul, S.; Bayrakci, M.
    New type of macrocyclic lactones functionalized with different groups were synthesized by reaction of the dihydroxy compounds such as 5a-d with suitable glycolyl chloride such as tri, tetra dicarboxylic acid dichloride derivatives. Their metal complexes with NaClO4.H2O, KCIO4 and Ba(ClO4)2.H2O were studied. Furthermore, their metal-pic-rate extraction studies with metal salts such as Na+, K+, Cu2+, Ni2+ and Hg2+ from aqueous phase to organic phase were attempted. All the structures of the ligands and complexes were confirmed by1H-, 13C-NMR, IR, UV-Vis, MS and elemental analyses methods.