İminooksimli schiff bazlarının sentezi ve geçiş metal komplekslerinin incelenmesi
Küçük Resim Yok
Tarih
2002
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Niğde Üniversitesi
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
ÖZET İMİNOOKSİMLİ SCHİFF BAZLARININ SENTEZİ VE GEÇİŞ METAL KOMPLEKSLERİNİN İNCELENMESİ UÇAN, Selma Yıldırım Niğde Üniversitesi Fen Bilimleri Enstitüsü Kimya Anabilim Dalı Danışman : Doç. Dr. Bedrettin MERCİMEK Ağustos, 2002, 110 sayfa Bu çalışmada çıkış maddesi olarak. 2-asetilnaftalin kullanıldı. 2-Asetilnaftalin sodyum etoksitli ortamda n-bütilnitrit ile nitrozolanarak izonitrozo-2-asetilnaftalin elde edildi. İsonitroso-2-asetilnaftalinin farklı aminler (metilamin, benzilamin, 1,2-diamino-propan ve etilendiamin) ile reaksiyonlarından dört yeni ligand; metiliminoisonitroso-2-asetilnaftalin, benziliminoisonitroso-2-asetilnaftalin, l,2-propilimino-bis(isonitroso-2-asetilnaftalin) ve 1,2-etilimino-bis(isonitroso-2-asetilnaftalin sentezlendi. Schiff bazlarının Ni(II), Cu(II), Co(II), Zn(II), Cd(II) ve Hg(II) asetat tuzları ile 24 kompleksi sentezlendi. Sentezlenen 28 yeni bileşiğin yapıları; elementel analiz, FT-1R, 'H-NMR, i3C-NMR, UV-Vis, magnetik susseptibilite ve MS yöntemleriyle aydınlatıldı. Anahtar Kelimeler : İminooksim, Schiff baz, metal kompleksler, m
SUMMARY SYNTHESIS OF İMİNEOXİME SCHİFF BASES AND INVESTIGATION OF THEIR TRANSITION METAL COMPLEXES UÇAN, Selma Yıldırım Niğde University Graduate School of Natural and Aplied Science Department of Chemistry Supervisor : Doç. Dr. Bedrettin MERCİMEK Agust200i, 110 pages In this work 2-acetylnaphthalene was used as a starting material. Isonitroso-2- acetylnaphthalene has been isolated through the nitrosation reaction between 2-acetylnaphthalene and butylnitrite in sodium ethoxide medium. Isonitroso-2- acetylnaphthalene was reacted with different amines (methylamine, benzylamino, 1,2-diaminopropane and 1,2-diaminoethane). As a result of these reactions, four new ligands; methyliminoisonitroso-2-acetylnaphthalene, benzyliminoisonitroso-2-acetyl- naphthalene, 1,2-prophylimino-bis(isonitroso-2-acetylnaphthalene) and 1,2-ethylimino- bis(isonitroso-2-acetylnaphthalene) were synthesized. The complexes of Schiff bases were synthesized by Ni(II), Cu(II), Co(II), Zn(II), Cd(ll) and Hg(II) acetat salts. As a conclusion of above work, four different ligands and their complexes were characterized by elementary analysis, IR, *H NMR, l3C-NMR, MS, UV-Vis ve Magnetic Susceptibility spectroscopy. Key Words: imineoxime, Schiff Base, Metal Complexes IV
SUMMARY SYNTHESIS OF İMİNEOXİME SCHİFF BASES AND INVESTIGATION OF THEIR TRANSITION METAL COMPLEXES UÇAN, Selma Yıldırım Niğde University Graduate School of Natural and Aplied Science Department of Chemistry Supervisor : Doç. Dr. Bedrettin MERCİMEK Agust200i, 110 pages In this work 2-acetylnaphthalene was used as a starting material. Isonitroso-2- acetylnaphthalene has been isolated through the nitrosation reaction between 2-acetylnaphthalene and butylnitrite in sodium ethoxide medium. Isonitroso-2- acetylnaphthalene was reacted with different amines (methylamine, benzylamino, 1,2-diaminopropane and 1,2-diaminoethane). As a result of these reactions, four new ligands; methyliminoisonitroso-2-acetylnaphthalene, benzyliminoisonitroso-2-acetyl- naphthalene, 1,2-prophylimino-bis(isonitroso-2-acetylnaphthalene) and 1,2-ethylimino- bis(isonitroso-2-acetylnaphthalene) were synthesized. The complexes of Schiff bases were synthesized by Ni(II), Cu(II), Co(II), Zn(II), Cd(ll) and Hg(II) acetat salts. As a conclusion of above work, four different ligands and their complexes were characterized by elementary analysis, IR, *H NMR, l3C-NMR, MS, UV-Vis ve Magnetic Susceptibility spectroscopy. Key Words: imineoxime, Schiff Base, Metal Complexes IV
Açıklama
Fen Bilimleri Enstitüsü, Kimya Ana Bilim Dalı
Anahtar Kelimeler
Kimya, Chemistry
