Synthesis, spectral, thermal, and magnetic studies of cobalt(II), nickel(II), copper(II), zinc(II), and cadmium(II) complexes with N2O2 donor groups
Küçük Resim Yok
Tarih
2014
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
MAIK NAUKA/INTERPERIODICA/SPRINGER
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
A new Schiff base ligand was prepared by condensation of 2-hydroxy-4-methoxybenzaldehyde with 1,2-propanediamine. The ligand and its metal complexes were characterized by elemental analysis, FT-IR, H-1 and C-13 NMR, magnetic moment, molar conductance, UV-Vis, SEM and thermal analysis (TGA). The molar conductance measurements indicated that all the metal complexes were non-electrolytes. IR spectra showed that ligand (L) behaves as a neutral tetradentate ligand and binds to the metal ions by the two azomethine nitrogen atoms and two phenolic oxygen atoms. The electronic absorption spectra and magnetic susceptibility measurements indicated square planar geometry for the Ni(II) and Cu(II) complexes while other metal complexes showed tetrahedral geometry. Also the surface morphology of the complexes was studied by SEM.
Açıklama
Anahtar Kelimeler
Kaynak
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
WoS Q Değeri
Q4
Scopus Q Değeri
Q4
Cilt
84
Sayı
9
