Synthesis, spectral, thermal, and magnetic studies of cobalt(II), nickel(II), copper(II), zinc(II), and cadmium(II) complexes with N2O2 donor groups
dc.contributor.author | Ucan, Selma Y. | |
dc.date.accessioned | 2019-08-01T13:38:39Z | |
dc.date.available | 2019-08-01T13:38:39Z | |
dc.date.issued | 2014 | |
dc.department | Niğde ÖHÜ | |
dc.description.abstract | A new Schiff base ligand was prepared by condensation of 2-hydroxy-4-methoxybenzaldehyde with 1,2-propanediamine. The ligand and its metal complexes were characterized by elemental analysis, FT-IR, H-1 and C-13 NMR, magnetic moment, molar conductance, UV-Vis, SEM and thermal analysis (TGA). The molar conductance measurements indicated that all the metal complexes were non-electrolytes. IR spectra showed that ligand (L) behaves as a neutral tetradentate ligand and binds to the metal ions by the two azomethine nitrogen atoms and two phenolic oxygen atoms. The electronic absorption spectra and magnetic susceptibility measurements indicated square planar geometry for the Ni(II) and Cu(II) complexes while other metal complexes showed tetrahedral geometry. Also the surface morphology of the complexes was studied by SEM. | |
dc.description.sponsorship | Research Foundation of the Nigde University (BAP) [P. N. FEB 2001-022] | |
dc.description.sponsorship | The author gratefully would like to thank the Research Foundation of the Nigde University (BAP) for financial support of this work (P. N. FEB 2001-022). | |
dc.identifier.doi | 10.1134/S1070363214090308 | |
dc.identifier.endpage | 1824 | |
dc.identifier.issn | 1070-3632 | |
dc.identifier.issn | 1608-3350 | |
dc.identifier.issue | 9 | |
dc.identifier.scopus | 2-s2.0-84910140474 | |
dc.identifier.scopusquality | Q4 | |
dc.identifier.startpage | 1819 | |
dc.identifier.uri | https://dx.doi.org/10.1134/S1070363214090308 | |
dc.identifier.uri | https://hdl.handle.net/11480/4128 | |
dc.identifier.volume | 84 | |
dc.identifier.wos | WOS:000343828700030 | |
dc.identifier.wosquality | Q4 | |
dc.indekslendigikaynak | Web of Science | |
dc.indekslendigikaynak | Scopus | |
dc.institutionauthor | Ucan, Selma Y. | |
dc.language.iso | en | |
dc.publisher | MAIK NAUKA/INTERPERIODICA/SPRINGER | |
dc.relation.ispartof | RUSSIAN JOURNAL OF GENERAL CHEMISTRY | |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | |
dc.rights | info:eu-repo/semantics/closedAccess | |
dc.title | Synthesis, spectral, thermal, and magnetic studies of cobalt(II), nickel(II), copper(II), zinc(II), and cadmium(II) complexes with N2O2 donor groups | |
dc.type | Article |