Synthesis, spectral, thermal, and magnetic studies of cobalt(II), nickel(II), copper(II), zinc(II), and cadmium(II) complexes with N2O2 donor groups

dc.contributor.authorUcan, Selma Y.
dc.date.accessioned2019-08-01T13:38:39Z
dc.date.available2019-08-01T13:38:39Z
dc.date.issued2014
dc.departmentNiğde ÖHÜ
dc.description.abstractA new Schiff base ligand was prepared by condensation of 2-hydroxy-4-methoxybenzaldehyde with 1,2-propanediamine. The ligand and its metal complexes were characterized by elemental analysis, FT-IR, H-1 and C-13 NMR, magnetic moment, molar conductance, UV-Vis, SEM and thermal analysis (TGA). The molar conductance measurements indicated that all the metal complexes were non-electrolytes. IR spectra showed that ligand (L) behaves as a neutral tetradentate ligand and binds to the metal ions by the two azomethine nitrogen atoms and two phenolic oxygen atoms. The electronic absorption spectra and magnetic susceptibility measurements indicated square planar geometry for the Ni(II) and Cu(II) complexes while other metal complexes showed tetrahedral geometry. Also the surface morphology of the complexes was studied by SEM.
dc.description.sponsorshipResearch Foundation of the Nigde University (BAP) [P. N. FEB 2001-022]
dc.description.sponsorshipThe author gratefully would like to thank the Research Foundation of the Nigde University (BAP) for financial support of this work (P. N. FEB 2001-022).
dc.identifier.doi10.1134/S1070363214090308
dc.identifier.endpage1824
dc.identifier.issn1070-3632
dc.identifier.issn1608-3350
dc.identifier.issue9
dc.identifier.scopus2-s2.0-84910140474
dc.identifier.scopusqualityQ4
dc.identifier.startpage1819
dc.identifier.urihttps://dx.doi.org/10.1134/S1070363214090308
dc.identifier.urihttps://hdl.handle.net/11480/4128
dc.identifier.volume84
dc.identifier.wosWOS:000343828700030
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorUcan, Selma Y.
dc.language.isoen
dc.publisherMAIK NAUKA/INTERPERIODICA/SPRINGER
dc.relation.ispartofRUSSIAN JOURNAL OF GENERAL CHEMISTRY
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.titleSynthesis, spectral, thermal, and magnetic studies of cobalt(II), nickel(II), copper(II), zinc(II), and cadmium(II) complexes with N2O2 donor groups
dc.typeArticle

Dosyalar