Substitüe salen komplekslerinin sentezi
Yükleniyor...
Tarih
2014
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Niğde Üniversitesi / Fen Bilimleri Enstitüsü
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
Bu çalışmada çıkış maddesi olarak 2,4-dihidroksi benzaldehit kullanıldı. 2,4-dihidroksi benzaldehit ile 1,2-fenilendiaminden reaksiyonundan; N,N'-Bis(2,4-dihidroksi benziliden)-fenilen-1,2-diamin sentezlendi. N,N'-Bis(2,4-dihidroksi benziliden)-fenilen-1,2-diamin ile N-(1-Pirenil) kloroasetamit'ten yeni bir Schiff baz ligandı sentezlendi. Schiff Bazının Ni(II), Cu(II), Co(II), Zn(II) ve Hg(II) asetatları ile beş metal kompleksi sentezlendi. Sentezlenen Sekiz yeni bileşiğin yapıları; Magnetik Susseptibilite, Molar İletkenlik, Elementel Analiz, FT-IR, 1H-NMR, UV-Vis,Floresans Spektroskopisive TGA yöntemleriyle aydınlatılmaya çalışıldı.
In this study 2,4-dihydroxy benzaldehyde was used as a starting meterial. N,N'-Bis(2,4-dihydroxybenzylidene)-phenylene-1,2-diamine was synthesized by using 2,4-dihydroxy benzaldehyde and 1,2-phenylenediamine. A new Schiff base ligand was synthesized by reaction with N,N'-Bis(2,4-dihydroxybenzylidene)-phenylene-1,2-diamine and N-(1-pyrenyl)chloroacetamide. Thecomplexes of Schiff base were synthesized by Ni(II), Cu(II), Co(II), Zn(II) and Hg(II) acetat salts. As a conclusion of above work, new one ligand and their complexes were characterized by FT-IR, 1H NMR, UV-Vis, TGA ve Magnetic Susceptibility, fluorescence spectroscopy, elementary analysis.
In this study 2,4-dihydroxy benzaldehyde was used as a starting meterial. N,N'-Bis(2,4-dihydroxybenzylidene)-phenylene-1,2-diamine was synthesized by using 2,4-dihydroxy benzaldehyde and 1,2-phenylenediamine. A new Schiff base ligand was synthesized by reaction with N,N'-Bis(2,4-dihydroxybenzylidene)-phenylene-1,2-diamine and N-(1-pyrenyl)chloroacetamide. Thecomplexes of Schiff base were synthesized by Ni(II), Cu(II), Co(II), Zn(II) and Hg(II) acetat salts. As a conclusion of above work, new one ligand and their complexes were characterized by FT-IR, 1H NMR, UV-Vis, TGA ve Magnetic Susceptibility, fluorescence spectroscopy, elementary analysis.
Açıklama
Anahtar Kelimeler
Schiff Bazı, Floresans Spektroskopisi, 1-Aminopren, N-(1-Pirenil)-2-kloroasetamit, Metal Kompleksler, Schiffbase, Fluorescencespectroscopy, 1-Aminopyrene, N-(1-pyrenyl)-2-chloroacetamide, Metal Complexes
Kaynak
WoS Q Değeri
Scopus Q Değeri
Cilt
Sayı
Künye
Atalmış, G. (2014). Substitüe salen komplekslerinin sentezi. (Yüksek Lisans Tezi) Niğde Üniversitesi, Fen Bilimleri Enstitüsü, Niğde
