N-(tiyofen-3-ilmetilen)piridin-4-amin ve pirol'ün yeni tip iletken kopolimerinin sentezi ve karakterizasyonu
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Date
2009
Authors
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Publisher
Niğde Üniversitesi
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info:eu-repo/semantics/openAccess
Abstract
Bu çalışmada ilk önce N-(tiyofen -3-ilmetilen)piridin-4-amin sentezlendi ve 1H-NMR ve FT/IR ile karakterize edildi. N-(tiyofen-3-ilmetilen)piridin-4-amin ile pirol'den yola çıkarak, asetonitril (AN)-dimetilsülfoksit (DMSO)/NaClO4-LiClO4 çözücü/destek elektrolit sisteminde elektrokimyasal polimerizasyon metodu ile poli(N-(tiyofen-3-ilmetilen)piridin-4-amin-ko-pirol) kopolimeri sentezlenmiştir. Kopolimerin karakterizasyonu FT/IR, CV, TGA-DTA ve SEM gibi analiz teknikleri ile yapılmıştır. Kopolimerin iletkenliği ise dört nokta tekniği ile belirlenmiştir.
In this study, N-(thiophene-3-ylmethylene)pyridine-4-amine was synthesized firstly, and characterized with the 1H-NMR and FT/IR spectra. N-(thiophene-3-ylmethylene)pyridine-4-amine-co-pyrolle copolymer was synthesized by electrochemical polymerization method in acetontrile (AN)-dimethylsulfoxide (DMSO)/NaClO4-LiClO4 solvent/support electrolyte system from N-(thiophene-3-ylmethylene)pyridine-4-amine and pyrolle. Characterization of copolymer was achieved by FT/IR, CV, TGA-DTA and SEM techniques. Conductivity of the copolymer has been determined with four probe technique.
In this study, N-(thiophene-3-ylmethylene)pyridine-4-amine was synthesized firstly, and characterized with the 1H-NMR and FT/IR spectra. N-(thiophene-3-ylmethylene)pyridine-4-amine-co-pyrolle copolymer was synthesized by electrochemical polymerization method in acetontrile (AN)-dimethylsulfoxide (DMSO)/NaClO4-LiClO4 solvent/support electrolyte system from N-(thiophene-3-ylmethylene)pyridine-4-amine and pyrolle. Characterization of copolymer was achieved by FT/IR, CV, TGA-DTA and SEM techniques. Conductivity of the copolymer has been determined with four probe technique.
Description
Fen Bilimleri Enstitüsü, Kimya Ana Bilim Dalı
Keywords
Polimer Bilim ve Teknolojisi, Polymer Science and Technology
