N-(tiyofen-3-ilmetilen)piridin-4-amin ve pirol'ün yeni tip iletken kopolimerinin sentezi ve karakterizasyonu
Küçük Resim Yok
Tarih
2009
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Niğde Üniversitesi
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
Bu çalışmada ilk önce N-(tiyofen -3-ilmetilen)piridin-4-amin sentezlendi ve 1H-NMR ve FT/IR ile karakterize edildi. N-(tiyofen-3-ilmetilen)piridin-4-amin ile pirol'den yola çıkarak, asetonitril (AN)-dimetilsülfoksit (DMSO)/NaClO4-LiClO4 çözücü/destek elektrolit sisteminde elektrokimyasal polimerizasyon metodu ile poli(N-(tiyofen-3-ilmetilen)piridin-4-amin-ko-pirol) kopolimeri sentezlenmiştir. Kopolimerin karakterizasyonu FT/IR, CV, TGA-DTA ve SEM gibi analiz teknikleri ile yapılmıştır. Kopolimerin iletkenliği ise dört nokta tekniği ile belirlenmiştir.
In this study, N-(thiophene-3-ylmethylene)pyridine-4-amine was synthesized firstly, and characterized with the 1H-NMR and FT/IR spectra. N-(thiophene-3-ylmethylene)pyridine-4-amine-co-pyrolle copolymer was synthesized by electrochemical polymerization method in acetontrile (AN)-dimethylsulfoxide (DMSO)/NaClO4-LiClO4 solvent/support electrolyte system from N-(thiophene-3-ylmethylene)pyridine-4-amine and pyrolle. Characterization of copolymer was achieved by FT/IR, CV, TGA-DTA and SEM techniques. Conductivity of the copolymer has been determined with four probe technique.
In this study, N-(thiophene-3-ylmethylene)pyridine-4-amine was synthesized firstly, and characterized with the 1H-NMR and FT/IR spectra. N-(thiophene-3-ylmethylene)pyridine-4-amine-co-pyrolle copolymer was synthesized by electrochemical polymerization method in acetontrile (AN)-dimethylsulfoxide (DMSO)/NaClO4-LiClO4 solvent/support electrolyte system from N-(thiophene-3-ylmethylene)pyridine-4-amine and pyrolle. Characterization of copolymer was achieved by FT/IR, CV, TGA-DTA and SEM techniques. Conductivity of the copolymer has been determined with four probe technique.
Açıklama
Fen Bilimleri Enstitüsü, Kimya Ana Bilim Dalı
Anahtar Kelimeler
Polimer Bilim ve Teknolojisi, Polymer Science and Technology
