Benzo-15-crown-5 içeren vic-dioksimler ve geçiş metal komplekslerinin sentezi
Küçük Resim Yok
Tarih
2002
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Niğde Üniversitesi
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
ÖZET BENZ015-CROWN-5 İÇEREN viç-DİOKSİMLER ve GEÇİŞ METAL KOMPLEKSLERİNİN SENTEZİ BATTALOGLU Rifat Niğde Üniversitesi Fen Bilimleri Enstitüsü Kimya Anabilim Dalı Danışman: Yrd. Doç. Dr. Ali İhsan PEKACAR Temmuz 2002, 106 sayfa Bu çalışmada, çıkış maddesi olarak 4'-asetilbenzo-15-crown-5 kullanıldı. 4'-asetilbenzo-15- crown-5, sodyum etoksitli ortamda n-bütilnitrit ile nitrozolanarak isonitroso-benzo-15-crown- 5 elde edildi. İsonitroso-benzo-15-crown-5'in sodyumasetat katalizörlüğünde hidroksilaminhidroklorür ile reaksiyonundan da benzo-15-crown-5 glioksim sentezi gerçekleştirildi. Elde edilen bu yeni glioksim bileşiği 20-25°C'de klorlanarak benzo-15- crown-5 kloroglioksim izole edildi. Benzo-15-crown-5 kloroglioksim'in değişik aminlerle reaksiyonu sonunda beş adet subsititüe amino-benzo-15-crown-5 glioksim bileşiği, Ligandlann alkollü çözeltilerine Ni(II), Cu(II) ve Co(II)'nin asetat tuzlan ilave edilerek de substitüe amin benzo-15-crown-5 glioksimin metal kompleksleri elde edildi. Sonuç olarak, beş ligand ve onbeş kompleks izole edildi. Sentezi yapılan tüm bileşiklerin yapılan; 'H-NMR, Kütle, İR spektrumları ve elementel analiz sonuçlan ile aydınlatıldı. Anahtar Sözcükler: Crown eter, benzo-15-crown-5, glioksim, vic-dioksimler. Ill
SUMMARY SYNTHESIS OF VIC-DIOXIMES WITH BENZO-15-CROWN-5 AND THEIR TRANSITION METAL COMPLEXES. BATTALO?LU Rifat Niğde University Graduate School of Natural and Applied Sciences Department of Chemistry Supervisor : Yrd. Doç. Dr. Ali İhsan PEKACAR July 2002, 106 pages In this study, 4'-acetybenzo-15-crown-5 was used as a starting material, lsonitrosobenzo-15- crown-5 has been isolated through the nitrosation reaction between 4'-acetybenzo-15-crown-5 and butyl nitrite in sodium ethoxide medium. Similarly benzo-15-crown-5 glyoxime has been synthesized by the reaction of isonitrosobenzo-15-crown-5 with hydroxilamine hydrochloride and sodiumacetate. Finally powdered benzo-15-crown-5 glyoxime suspended in dry chloroform at 20-25°C and upon treatment with Cİ2, benzo-15-crown-5 chloroglyoxime was obtained. By reacting benzo-15-crown-5 chloroglyoxime with various amines, five different sustitued amino benzo-15-crown-5 glyoxime were synthesized. The complexes of substitued amino benzo-15-crown-5 glyoxime were prepared by adding solutions of Ni(H), Cu(II) and Co(II) into alcoholic solutions of the ligands. As a conclusion of above work 5 separate ligands and 15 complexes were isolated and their structures characters were determined employing by 'H-NMR, IR and elemental analytical techniques. Key Words: Crown ether, benzo-15-crown-5, glyoxime, vic-dioximes. IV
SUMMARY SYNTHESIS OF VIC-DIOXIMES WITH BENZO-15-CROWN-5 AND THEIR TRANSITION METAL COMPLEXES. BATTALO?LU Rifat Niğde University Graduate School of Natural and Applied Sciences Department of Chemistry Supervisor : Yrd. Doç. Dr. Ali İhsan PEKACAR July 2002, 106 pages In this study, 4'-acetybenzo-15-crown-5 was used as a starting material, lsonitrosobenzo-15- crown-5 has been isolated through the nitrosation reaction between 4'-acetybenzo-15-crown-5 and butyl nitrite in sodium ethoxide medium. Similarly benzo-15-crown-5 glyoxime has been synthesized by the reaction of isonitrosobenzo-15-crown-5 with hydroxilamine hydrochloride and sodiumacetate. Finally powdered benzo-15-crown-5 glyoxime suspended in dry chloroform at 20-25°C and upon treatment with Cİ2, benzo-15-crown-5 chloroglyoxime was obtained. By reacting benzo-15-crown-5 chloroglyoxime with various amines, five different sustitued amino benzo-15-crown-5 glyoxime were synthesized. The complexes of substitued amino benzo-15-crown-5 glyoxime were prepared by adding solutions of Ni(H), Cu(II) and Co(II) into alcoholic solutions of the ligands. As a conclusion of above work 5 separate ligands and 15 complexes were isolated and their structures characters were determined employing by 'H-NMR, IR and elemental analytical techniques. Key Words: Crown ether, benzo-15-crown-5, glyoxime, vic-dioximes. IV
Açıklama
Bu tezin, veri tabanı üzerinden yayınlanma izni bulunmamaktadır. Yayınlanma izni olmayan tezlerin basılı kopyalarına Üniversite kütüphaneniz aracılığıyla (TÜBESS üzerinden) erişebilirsiniz.
Fen Bilimleri Enstitüsü, Kimya Ana Bilim Dalı
Fen Bilimleri Enstitüsü, Kimya Ana Bilim Dalı
Anahtar Kelimeler
Kimya, Chemistry
