Bis(amino)phosphines Derived From N-phenylpiperazine and N-ethylpiperazine: Synthesis, Oxidation Reactions, and Molybdenum Complexes
Küçük Resim Yok
Tarih
2013
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
TAYLOR & FRANCIS INC
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Functionalized bis(amino)phosphines that are the type PhP(NR2)2 (1,2) have been synthesized by treating PhPCl2 with N-phenylpiperazine or N-ethylpiperazine. Ligands react with aqueous hydrogen peroxide, elemental sulfur, or selenium to give the corresponding chalcogenides (38) in good yield. The molybdenum complexes of the bis(amino)phosphines (9,10) have been obtained. All of the compounds obtained in good yields and they were characterized by IR, NMR, microanalysis, and also quantum chemical calculations such as HOMO-LUMO energies, Mulliken charges, and dipole moment for compounds 18 and complex 9 were carried out by using B3LYP/6-31G(d,p), a version of the DFT method with standard Gaussian 09 software package program.
Açıklama
Anahtar Kelimeler
aminophosphines, oxidation, quantum chemical calculations, synthesis
Kaynak
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY
WoS Q Değeri
Q4
Scopus Q Değeri
N/A
Cilt
43
Sayı
2
